Chemical Datasheet
TRICRESYL PHOSPHATE |
|
Chemical Identifiers
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The
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include common identification numbers, the
NFPA diamond
U.S. Department of Transportation hazard labels, and a general
description of the chemical. The information in CAMEO Chemicals comes
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| CAS Number | UN/NA Number | DOT Hazard Label | USCG CHRIS Code |
|---|---|---|---|
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|
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| NIOSH Pocket Guide | International Chem Safety Card | ||
Triorthocresyl phosphate
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NFPA 704
| Diamond | Hazard | Value | Description | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
Health
|
1 | Can cause significant irritation. | |||||||||
Flammability
|
1 | Must be preheated before ignition can occur. | ||||||||||
Instability
|
0 | Normally stable, even under fire conditions. | ||||||||||
Special
|
(NFPA, 2010)
General Description
A colorless,odorless liquid. Insoluble in water and slightly denser than water. Toxic by ingestion and skin absorption. Used to make plastics and lubricants.
Hazards
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The
Hazard fields
include
special hazard alerts
air and water
reactions, fire hazards, health hazards, a reactivity profile, and
details about
reactive groups assignments
and
potentially incompatible absorbents.
The information in CAMEO Chemicals comes from a variety of
data sources.
Reactivity Alerts
none
Air & Water Reactions
Insoluble in water.
Fire Hazard
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways. (ERG, 2024)
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways. (ERG, 2024)
Health Hazard
Vapors may irritate eyes, but only at high temperatures. Ingestion of liquid may cause severe damage to central nervous system and death if significant amounts of the toxic ortho-isomer are present. (USCG, 1999)
Reactivity Profile
Organophosphates, such as TRICRESYL PHOSPHATE, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
No information available.
Response Recommendations
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The
Response Recommendation fields
include isolation and evacuation distances, as well as recommendations for
firefighting, non-fire response, protective clothing, and first aid. The
information in CAMEO Chemicals comes from a variety of
data sources.
Isolation and Evacuation
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
SMALL FIRE: Dry chemical, CO2 or water spray.
LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal. Avoid aiming straight or solid streams directly onto the product.
FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)
SMALL FIRE: Dry chemical, CO2 or water spray.
LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal. Avoid aiming straight or solid streams directly onto the product.
FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)
Non-Fire Response
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. For solids, prevent dust cloud and avoid inhalation of dust. (ERG, 2024)
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. For solids, prevent dust cloud and avoid inhalation of dust. (ERG, 2024)
Protective Clothing
Excerpt from NIOSH Pocket Guide for Triorthocresyl phosphate:
Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.
Eyes: No recommendation is made specifying the need for eye protection.
Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.
Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Change: No recommendation is made specifying the need for the worker to change clothing after the workshift. (NIOSH, 2024)
:Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.
Eyes: No recommendation is made specifying the need for eye protection.
Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.
Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Change: No recommendation is made specifying the need for the worker to change clothing after the workshift. (NIOSH, 2024)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, administer a slurry of activated charcoal in water and simultaneously call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, administer a slurry of activated charcoal in water and simultaneously call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Physical Properties
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The
Physical Property fields
include properties such as vapor pressure and
boiling point, as well as explosive limits and
toxic exposure thresholds
The information in CAMEO Chemicals comes from a variety of
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Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
| Chemical Formula: |
|
Flash Point:
437°F
(NTP, 1992)
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature:
725°F
(NTP, 1992)
Melting Point:
-22 to -13°F
(NTP, 1992)
Vapor Pressure:
1.7e-06 mmHg
at 77°F
(NTP, 1992)
Vapor Density (Relative to Air):
12.7
(NTP, 1992)
- Heavier than air; will sink
Specific Gravity:
1.16
at 68°F
(USCG, 1999)
- Denser than water; will sink
Boiling Point:
770°F
at 760 mmHg
(Slight decomposition)
(NTP, 1992)
Molecular Weight:
368.37
(NTP, 1992)
Water Solubility:
less than 1 mg/mL
at 68°F
(NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH:
40 mg/m3
[From NPG: Triorthocresyl phosphate]
(NIOSH, 2024)
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.PACs (Protective Action Criteria)
| Chemical | PAC-1 | PAC-2 | PAC-3 |
|---|---|---|---|
| Tri-o-tolyl phosphate; (Triorthocresyl phosphate) (78-30-8) | 0.3 ppm | 13 ppm | 40 ppm |
(DOE, 2024)
Regulatory Information
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The
Regulatory Information fields
include information from
the U.S. Environmental Protection Agency's Title III Consolidated List of
Lists,
the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility
Anti-Terrorism Standards,
and the U.S. Occupational Safety and Health Administration's
Process Safety Management of Highly Hazardous Chemicals Standard List
(see more about these
data sources).
EPA Consolidated List of Lists
No regulatory information available.CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.OSHA Process Safety Management (PSM) Standard List
No regulatory information available.Alternate Chemical Names
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This section provides a listing of alternate names for this chemical,
including trade names and synonyms.
- CELLUFLEX 179C
- CRESYL PHOSPHATE
- DISFLAMOLL TKP
- DURAD 124
- DURAD 125
- FYRQUEL 150
- IMOL S 140
- KRONITEX
- KRONITEX R
- KRONITEX TCP
- LINDOL
- NISSAN UNFLAME TCP
- O-CRESYL PHOSPHATE
- O-CRESYLPHOSPHATE
- O-TOLYL PHOSPHATE
- O-TOLYLPHOSPHATE PHOSPHORIC ACID
- PHOSFLEX 179-C
- PHOSFLEX 179C
- PHOSPHLEX 179A
- PHOSPHORIC ACID TRICRESYL ESTER
- PHOSPHORIC ACID, TRI-O-CRESYL ETHER
- PHOSPHORIC ACID, TRI-O-TOLYL ESTER
- PHOSPHORIC ACID, TRIS(2-METHYLPHENYL) ESTER
- PHOSPHORIC ACID, TRITOLYL ESTER
- REOMOL TCP
- SANSOCIZER TCP
- SUMIGUARD TBT
- SYN-O-AD 8484
- TCP
- TOCP
- TOFK
- TOKF
- TOTP
- TRI-2-METHYLPHENYL PHOSPHATE
- TRI-2-TOLYL PHOSPHATE
- TRI-O-CRESYL ESTER
- TRI-O-CRESYL ESTER OF PHOSPHORIC ACID
- TRI-O-CRESYL PHOSPHATE
- TRI-O-TOLYL ESTER PHOSPHORIC ACID
- TRI-O-TOLYL PHOSPHATE
- TRI-P-CRESYL PHOSPHATE
- TRI-P-TOLYL PHOSPHATE
- TRICRESOL PHOSPHATE
- TRICRESYL ORTHOPHOSPHATE
- TRICRESYL PHOSPHATE
- TRICRESYL PHOSPHATE (<1% ORTHO ISOMER)
- TRICRESYL PHOSPHATE (>= 1% ORTHO ISOMER)
- TRICRESYLPHOSPHATE
- TRIORTHOCRESYL PHOSPHATE
- TRIS(METHYLPHENYL) PHOSPHATE
- TRIS(O-CRESYL) PHOSPHATE
- TRIS(O-METHYLPHENYL) PHOSPHATE
- TRIS(O-TOLYL) PHOSPHATE
- TRIS(TOLYLOXY)PHOSPHINE OXIDE
- TRITOLYL PHOSPHATE
Web site owner:
Office of Response and Restoration,
National Ocean Service,
National Oceanic and Atmospheric Administration.
USA.gov.
CAMEO Chemicals version 3.1.0 rev 1.