|CAS Number||UN/NA Number||DOT Hazard Label||USCG CHRIS Code|
|NIOSH Pocket Guide||International Chem Safety Card|
- Highly Flammable
ACUTE/CHRONIC HAZARDS: This compound is a skin irritant and sensitizer. It is also an eye irritant. It may be harmful by ingestion, inhalation or skin absorption. When heated to decomposition it emits acrid smoke and toxic fumes of carbon monoxide and carbon dioxide. (NTP, 1992)
Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below. More info about absorbents, including situations to watch out for...
As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
STORAGE PRECAUTIONS: You should protect this chemical from exposure to light. Keep the container tightly closed under an inert atmosphere, and store under refrigerated temperatures. (NTP, 1992)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with a combination filter cartridge, i.e. organic vapor/acid gas/HEPA (specific for organic vapors, HCl, acid gas, SO2 and a high efficiency particulate filter).
RECOMMENDED GLOVE MATERIALS: If this chemical makes direct contact with your gloves, or if a tear, puncture or hole develops, replace them at once.
Glove Type Model Number Thickness Bkthru Time
Polyvinyl alcohol Edmont 25-545 0.23 mm 480 min
Nitrile Edmont 37-155 0.38 mm 480 min
Viton North F-091 0.23 mm 480 min
Neoprene Edmont 29-870 0.43 mm 60 min (NTP, 1992)
|QS = Tychem 2000 SFR|
|QC = Tychem 2000|
|SL = Tychem 4000|
|C3 = Tychem 5000|
|TF = Tychem 6000|
|TP = Tychem 6000 FR|
|BR = Tychem 9000|
|RC = Tychem RESPONDER® CSM|
|TK = Tychem 10000|
|RF = Tychem 10000 FR|
A blank cell indicates the fabric has not been tested. The fabric may or may not offer barrier.
Special Warnings from DuPont
- Serged and bound seams are degraded by some hazardous liquid chemicals, such as strong acids, and should not be worn when these chemicals are present.
CAUTION: This information is based upon technical data that
DuPont believes to be reliable. It is subject to revision as
additional knowledge and experience are gained. DuPont makes no
guarantee of results and assumes no obligation or liability...
... in connection with this information. It is the user's responsibility to determine the level of toxicity and the proper personal protective equipment needed. The information set forth herein reflects laboratory performance of fabrics, not complete garments, under controlled conditions. It is intended for informational use by persons having technical skill for evaluation under their specific end-use conditions, at their own discretion and risk. Anyone intending to use this information should first verify that the garment selected is suitable for the intended use. In many cases, seams and closures have shorter breakthrough times and higher permeation rates than the fabric. Please contact DuPont for specific data. If fabric becomes torn, abraded or punctured, or if seams or closures fail, or if attached gloves, visors, etc. are damaged, end user should discontinue use of garment to avoid potential exposure to chemical. Since conditions of use are outside our control, we make no warranties, express or implied, including, without limitation, no warranties of merchantability or fitness for a particular use and assume no liability in connection with any use of this information. This information is not intended as a license to operate under or a recommendation to infringe any patent or technical information of DuPont or others covering any material or its use.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital.
OTHER: Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring. Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)
AEGLs (Acute Exposure Guideline Levels)No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)No ERPG information available.
PACs (Protective Action Criteria)
|Limonene, d- (5989-27-5)||15 ppm||67 ppm||170 ppm|
EPA Consolidated List of ListsNo regulatory information available.
DHS Chemical Facility Anti-Terrorism Standards (CFATS)No regulatory information available.
OSHA Process Safety Management (PSM) Standard ListNo regulatory information available.
Alternate Chemical Names
- BIOGENIC SE 374
- CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-, (R)-
- EC 7
- LIMONENE, (+)-
- P-MENTHA-1,8-DIENE, (R)-(+)-