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Chemical Datasheet


8 - Corrosive
Chemical Identifiers | Hazards | Response Recommendations | Physical Properties | Regulatory Information | Alternate Chemical Names

Chemical Identifiers

The Chemical Identifier fields include common identification numbers, the NFPA diamond, U.S. Department of Transportation hazard labels, and a general description of the chemical. The information in CAMEO Chemicals comes from a variety of data sources..
CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 1310-73-2
  • Corrosive
NFPA 704
Diamond Hazard Value Description
3 1
Blue Health 3 Can cause serious or permanent injury.
Red Flammability 0 Will not burn under typical fire conditions.
Yellow Instability 1 Normally stable but can become unstable at elevated temperatures and pressures.
White Special
(NFPA, 2010)
NIOSH Pocket Guide International Chem Safety Card
Sodium hydroxideexternal link
General Description
A white solid. Corrosive to metals and tissue. Used in chemical manufacturing, petroleum refining, cleaning compounds, drain cleaners.


The Hazard fields include special hazard alerts, air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The information in CAMEO Chemicals comes from a variety of data sources.
Reactivity Alerts
Air & Water Reactions
Soluble in water. Dissolution can liberate enough heat to cause steaming and spattering and ignite adjacent combustible material [Haz. Chem. Data 1966].
Fire Hazard
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. For electric vehicles or equipment, ERG Guide 147 (lithium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. (ERG, 2016)
Health Hazard
Strong corrosive action on contacted tissues. INHALATION: dust may cause damage to upper respiratory tract and lung itself, producing from mild nose irritation to pneumonitis. INGESTION: severe damage to mucous membranes; severe scar formation or perforation may occur. EYE CONTACT: produces severe damage. (USCG, 1999)
Reactivity Profile
SODIUM HYDROXIDE (Caustic Soda) is a strong base. Reacts rapidly and exothermically with acids, both organic and inorganic. Readily absorbs moisture from the air to give caustic semi-solids that attack aluminum and zinc with the evolution of flammable hydrogen gas. Catalyzes the polymerization of acetaldehyde and other polymerizable compounds; these reactions can occur violently, for example, acrolein polymerizes with extreme violence when put in contact with alkaline materials such as sodium hydroxide [Chem. Safety Data Sheet SD-85 1961]. Reacts with great violence with phosphorus pentaoxide when initiated by local heating [Mellor 8 Supp.3:406 1971]. Contact (as a drying agent) with tetrahydrofuran, which often contains peroxides, may be hazardous---explosions have occurred in such a use of the chemically similar potassium hydroxide [NSC Newsletter Chem. Soc. 1967]. Mixing with any of the following substances in a closed container caused the temperature and pressure to increase: glacial acetic acid, acetic anhydride, acrolein, chlorohydrin, chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrochloric acid (36%), hydrofluoric acid (48.7%), nitric acid (70%), oleum, propiolactone, sulfuric acid (96%) [NFPA 1991]. Accidental contact between a caustic cleaning solution (probably containing sodium hydroxide) and Pentol caused a violent explosion. [MCA Case History 363(1964)]. Heating with a mixture of methyl alcohol and trichlorobenzene during an attempted synthesis led to a sudden increase in pressure and an explosion [MCA Guide for Safety Appendix 3 1972]. Hot and/or concentrated NaOH can cause hydroquinone to decompose exothermically at elevated temperature. (NFPA Pub. 491M, 1975, 385)
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below. More info about absorbents, including situations to watch out for...

Response Recommendations

The Response Recommendation fields include isolation and evacuation distances, as well as recommendations for firefighting, non-fire response, protective clothing, and first aid. The information in CAMEO Chemicals comes from a variety of data sources.
Isolation and Evacuation
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

SMALL FIRE: Dry chemical, CO2 or water spray.

LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)
Non-Fire Response
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2016)
Protective Clothing
Skin: Wear appropriate personal protective clothing to prevent skin contact.

Eyes: Wear appropriate eye protection to prevent eye contact.

Wash skin: The worker should immediately wash the skin when it becomes contaminated.

Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premise.

Provide: Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substance; this is irrespective of the recommendation involving the wearing of eye protection. Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2016)
DuPont Tychem® Suit Fabrics
Tychem® Fabric Legend
QC = Tychem QC
SL = Tychem SL
TF = Tychem F
TP = Tychem ThermoPro
C3 = Tychem CPF 3
BR = Tychem BR
RC = Tychem Responder® CSM
TK = Tychem TK
RF = Tychem Reflector®
Testing Details
Permeation data obtained per ASTM F739. Normalized breakthrough times (the time at which the permeation rate is equal to 0.1 µg/cm2/min) reported in minutes. All liquid chemicals have been tested between approximately 20°C and 27°C unless otherwise stated. All chemicals have been tested at a concentration of greater than 95% unless otherwise stated. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% relative humidity per military standard MIL-STD-282.
Normalized Breakthrough Times (in Minutes)
Chemical CAS Number State QC SL TF TP C3 BR RC TK RF
Caustic soda (40%) 1310-73-2 Liquid
Caustic soda (50%) 1310-73-2 Liquid >480 >480 >480 >480 >480 >480 >480 >480 >480
Lye (40%) 1310-73-2 Liquid
Lye (50%) 1310-73-2 Liquid >480 >480 >480 >480 >480 >480 >480 >480 >480
NaOH (Sodium hydroxide) (40%) 1310-73-2 Liquid
NaOH (Sodium hydroxide) (50%) 1310-73-2 Liquid >480 >480 >480 >480 >480 >480 >480 >480 >480
Sodium hydroxide (40%) 1310-73-2 Liquid
Sodium hydroxide (50%) 1310-73-2 Liquid >480 >480 >480 >480 >480 >480 >480 >480 >480
> indicates greater than.
A blank cell indicates the fabric has not been tested. The fabric may or may not offer barrier.

Special Warnings from DuPont

  1. Serged and bound seams are degraded by some hazardous liquid chemicals, such as strong acids, and should not be worn when these chemicals are present.
  2. CAUTION: This information is based upon technical data that DuPont believes to be reliable. It is subject to revision as additional knowledge and experience are gained. DuPont makes no guarantee of results and assumes no obligation or liability...
    ... in connection with this information. It is the user's responsibility to determine the level of toxicity and the proper personal protective equipment needed. The information set forth herein reflects laboratory performance of fabrics, not complete garments, under controlled conditions. It is intended for informational use by persons having technical skill for evaluation under their specific end-use conditions, at their own discretion and risk. Anyone intending to use this information should first verify that the garment selected is suitable for the intended use. In many cases, seams and closures have shorter breakthrough times and higher permeation rates than the fabric. Please contact DuPont for specific data. If fabric becomes torn, abraded or punctured, or if seams or closures fail, or if attached gloves, visors, etc. are damaged, end user should discontinue use of garment to avoid potential exposure to chemical. Since conditions of use are outside our control, we make no warranties, express or implied, including, without limitation, no warranties of merchantability or fitness for a particular use and assume no liability in connection with any use of this information. This information is not intended as a license to operate under or a recommendation to infringe any patent or technical information of DuPont or others covering any material or its use.

(DuPont, 2016)

First Aid
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.

Skin: If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.

Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible.

Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2016)

Physical Properties

The Physical Property fields include properties such as vapor pressure and boiling point, as well as explosive limits and toxic exposure thresholds. The information in CAMEO Chemicals comes from a variety of data sources.
Chemical Formula:
  • NaOH
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: Not flammable (USCG, 1999)
Melting Point: 604 ° F (USCG, 1999)
Vapor Pressure: 0 mm Hg (approx) (NIOSH, 2016)
Vapor Density (Relative to Air): data unavailable
Specific Gravity: 2.13 at 68 ° F (USCG, 1999)
Boiling Point: Very high (USCG, 1999)
Molecular Weight: 40 (USCG, 1999)
Water Solubility: 111 % (NIOSH, 2016)
Ionization Potential: data unavailable
IDLH: 10 mg/m3 (NIOSH, 2016)

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

Chemical ERPG-1 ERPG-2 ERPG-3
Sodium Hydroxide (1310-73-2) 0.5 mg/m3 5 mg/m3 50 mg/m3
(AIHA, 2016)

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Sodium hydroxide (1310-73-2) 0.5 mg/m3 5 mg/m3 50 mg/m3
(DOE, 2016)

Regulatory Information

The Regulatory Information fields include information from the U.S. Environmental Protection Agency's Title III Consolidated List of Lists and the U.S. Department of Homeland Security's Chemical Facility Anti-Terrorism Standards (see more about these data sources).

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
CAA 112(r)
Sodium hydroxide 1310-73-2 1000 pounds

(EPA List of Lists, 2015)

DHS Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

Alternate Chemical Names

This section provides a listing of alternate names for this chemical, including trade names and synonyms.