Chemical Datasheet
TNT, WETTED WITH NOT LESS THAN 30% WATER |
Chemical Identifiers
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Chemical Identifier fields
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U.S. Department of Transportation hazard labels, and a general
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CAS Number | UN/NA Number | DOT Hazard Label | USCG CHRIS Code |
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|
none | |
NIOSH Pocket Guide | International Chem Safety Card | ||
2,4,6-Trinitrotoluene |
NFPA 704
data unavailable
General Description
A slurry of a yellow water-insoluble crystalline solid. Can burn, although difficult to ignite. When water has been driven off or evaporated the residue is easily ignited, burns vigorously, and is highly explosive. Produces toxic oxides of nitrogen during combustion. May explode under exposure to intense heat. Primary hazard is blast of an explosion, not flying projectiles or fragments.
Hazards
The
Hazard fields
include
special hazard alerts
air and water
reactions, fire hazards, health hazards, a reactivity profile, and
details about
reactive groups assignments
and
potentially incompatible absorbents.
The information in CAMEO Chemicals comes from a variety of
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Reactivity Alerts
- Strong Oxidizing Agent
Air & Water Reactions
No rapid reaction with air. No rapid reaction with water.
Fire Hazard
Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:
Flammable/combustible material. May be ignited by heat, sparks or flames. DRIED OUT material may explode if exposed to heat, flame, friction or shock; treat as an explosive (ERG Guide 112). Keep material wet with water or treat as an explosive (ERG Guide 112). Runoff to sewer may create fire or explosion hazard. (ERG, 2024)
Flammable/combustible material. May be ignited by heat, sparks or flames. DRIED OUT material may explode if exposed to heat, flame, friction or shock; treat as an explosive (ERG Guide 112). Keep material wet with water or treat as an explosive (ERG Guide 112). Runoff to sewer may create fire or explosion hazard. (ERG, 2024)
Health Hazard
Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:
Some are toxic and may be fatal if inhaled, ingested or absorbed through skin. Specifically, Dinitrophenol, wetted (UN1320); Dinitrophenolates, wetted (UN1321), Sodium dinitro-o-cresolate, wetted (UN1348); and Barium azide, wetted (UN1571) are known to be toxic. Contact may cause burns to skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2024)
Some are toxic and may be fatal if inhaled, ingested or absorbed through skin. Specifically, Dinitrophenol, wetted (UN1320); Dinitrophenolates, wetted (UN1321), Sodium dinitro-o-cresolate, wetted (UN1348); and Barium azide, wetted (UN1571) are known to be toxic. Contact may cause burns to skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2024)
Reactivity Profile
TNT (trinitrotoluene) may begin a vigorous reaction that culminates in a detonation if mixed with reducing agents, including hydrides, sulfides and nitrides. May explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below. More info about absorbents, including situations to watch out for...
- Cellulose-Based Absorbents
- Expanded Polymeric Absorbents
Response Recommendations
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Response Recommendation fields
include isolation and evacuation distances, as well as recommendations for
firefighting, non-fire response, protective clothing, and first aid. The
information in CAMEO Chemicals comes from a variety of
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Isolation and Evacuation
Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions.
LARGE SPILL: Consider initial evacuation for 500 meters (1/3 mile) in all directions.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions.
LARGE SPILL: Consider initial evacuation for 500 meters (1/3 mile) in all directions.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:
CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed to heat.
TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned master stream devices or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe distance, with extinguisher ready for possible re-ignition. (ERG, 2024)
CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed to heat.
TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned master stream devices or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe distance, with extinguisher ready for possible re-ignition. (ERG, 2024)
Non-Fire Response
Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material.
SMALL SPILL: Flush area with large amounts of water.
LARGE SPILL: Wet down with water and dike for later disposal. KEEP "WETTED" PRODUCT WET BY SLOWLY ADDING FLOODING QUANTITIES OF WATER. (ERG, 2024)
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material.
SMALL SPILL: Flush area with large amounts of water.
LARGE SPILL: Wet down with water and dike for later disposal. KEEP "WETTED" PRODUCT WET BY SLOWLY ADDING FLOODING QUANTITIES OF WATER. (ERG, 2024)
Protective Clothing
Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:
Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)
Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:
Refer to the "General First Aid" section. (ERG, 2024)
Refer to the "General First Aid" section. (ERG, 2024)
Physical Properties
The
Physical Property fields
include properties such as vapor pressure and
boiling point, as well as explosive limits and
toxic exposure thresholds
The information in CAMEO Chemicals comes from a variety of
data sources.
Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
Chemical Formula: |
|
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight: data unavailable
Water Solubility: data unavailable
Ionization Energy/Potential:
10.59 eV
[From NPG: 2,4,6-Trinitrotoluene]
(NIOSH, 2024)
IDLH:
500 mg/m3
[From NPG: 2,4,6-Trinitrotoluene]
(NIOSH, 2024)
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.PACs (Protective Action Criteria)
Chemical | PAC-1 | PAC-2 | PAC-3 |
---|---|---|---|
Trinitrotoluene, 2,4,6- (118-96-7) | 0.3 mg/m3 | 17 mg/m3 | 1000 mg/m3 |
(DOE, 2024)
Regulatory Information
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Regulatory Information fields
include information from
the U.S. Environmental Protection Agency's Title III Consolidated List of
Lists,
the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility
Anti-Terrorism Standards,
and the U.S. Occupational Safety and Health Administration's
Process Safety Management of Highly Hazardous Chemicals Standard List
(see more about these
data sources).
EPA Consolidated List of Lists
No regulatory information available.CISA Chemical Facility Anti-Terrorism Standards (CFATS)
RELEASE | THEFT | SABOTAGE | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
Chemical of Interest | CAS Number | Min Conc | STQ | Security Issue |
Min Conc | STQ | Security Issue |
Min Conc | STQ | Security Issue |
TNT; [Trinitrotoluene] | 118-96-7 | ACG | 5000 pounds | explosive | ACG | 400 pounds | EXP/IEDP |
- ACG = a commercial grade.
- EXP/IEDP = explosives/improvised explosive device precursors.
(CISA, 2007)
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.Alternate Chemical Names
This section provides a listing of alternate names for this chemical,
including trade names and synonyms.
- TNT, WETTED WITH NOT LESS THAN 30% WATER
- TRINITROTOLUENE, WETTED WITH NOT LESS THAN 30% WATER
- TRINITROTOLUENE, [WET, WITH >= 10% WATER]