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Chemical Datasheet

TABUN

6.1 - Poison
Chemical Identifiers | Hazards | Response Recommendations | Physical Properties | Regulatory Information | Alternate Chemical Names

Chemical Identifiers

The Chemical Identifier fields include common identification numbers, the NFPA diamond, U.S. Department of Transportation hazard labels, and a general description of the chemical. The information in CAMEO Chemicals comes from a variety of data sources..
CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 77-81-6
  • Poison
none
NFPA 704
data unavailable
NIOSH Pocket Guide International Chem Safety Card
none none
General Description
Colorless to brown liquid with a faint fruity odor. Used as a chemical warfare agent.

Hazards

The Hazard fields include special hazard alerts, air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The information in CAMEO Chemicals comes from a variety of data sources.
Reactivity Alerts
none
Air & Water Reactions
Hydrolysis forms hydrogen cyanide.
Fire Hazard
Extremely poisonous. (Non-Specific -- Poison A, Liquid) Keep away from sparks, flames, and sources of ignition. Keep out of water sources and sewers. Hydrolysis forms hydrogen cyanide. When heated to decomposition, it emits very toxic fumes of oxides of phosphorus and nitrogen. Avoid water and acids. Can react with oxidizing materials. (EPA, 1998)
Health Hazard
This material is toxic by inhalation and by absorption through skin and eyes. The lethal dose for humans may be as low as 0.01 mg/kg. Tabun is a nerve agent; it acts as a cholinesterase inhibitor. The median lethal dosage (respiratory) is 400 mg-minute/m3 for humans; the median incapacitating dosage is 300 mg-minute/m3. Respiratory lethal dosages kill in 1 to 10 minutes; liquid in the eye kills nearly as rapidly. Skin absorption great enough to cause death may occur in 1 to 2 minutes, but may be delayed for 1 to 2 hours. (EPA, 1998)
Reactivity Profile
When heated to decomposition, TABUN emits very toxic fumes of oxides of phosphorus and nitrogen. Avoid water and acids. Can react with oxidizing materials. [EPA, 1998].
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below. More info about absorbents, including situations to watch out for...

Response Recommendations

The Response Recommendation fields include isolation and evacuation distances, as well as recommendations for firefighting, non-fire response, protective clothing, and first aid. The information in CAMEO Chemicals comes from a variety of data sources.
Isolation and Evacuation
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:

As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: If this material is being used as a weapon, see ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 2810 datasheet. Otherwise increase, in the downwind direction, as necessary, the isolation distance shown above.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Firefighting
Complete protection required; have available decontaminants (bleach, alkali) and atropine. Bleaching powder (chlorinated line) destroys Tabun but gives rise to cyanogen chloride.

(Non-Specific -- Poison A, Liquid) Extinguish with alcohol foam, carbon dioxide, or dry chemical. (EPA, 1998)
Non-Fire Response
(Non-Specific -- Poison A, Liquid) When handling, avoid breathing vapors, keep upwind, avoid bodily contact with the material, and upon skin contact wash with soap and water. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes. (EPA, 1998)
Protective Clothing
For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)
DuPont Tychem® Suit Fabrics
Tychem® Fabric Legend
QC = Tychem QC
SL = Tychem SL
TF = Tychem F
TP = Tychem ThermoPro
C3 = Tychem CPF 3
BR = Tychem BR
RC = Tychem Responder® CSM
TK = Tychem TK
RF = Tychem Reflector®
Testing Details
Permeation data obtained per ASTM F739. Normalized breakthrough times (the time at which the permeation rate is equal to 0.1 µg/cm2/min) reported in minutes. All liquid chemicals have been tested between approximately 20°C and 27°C unless otherwise stated. All chemicals have been tested at a concentration of greater than 95% unless otherwise stated. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% relative humidity per military standard MIL-STD-282.
Normalized Breakthrough Times (in Minutes)
Chemical CAS Number State QC SL TF TP C3 BR RC TK RF
Tabun (10 g/m²) 77-81-6 Liquid >480 >480 >480 >480
Tabun (100 g/m²) 77-81-6 Liquid >480 >480 >480
> indicates greater than.
A blank cell indicates the fabric has not been tested. The fabric may or may not offer barrier.

Special Warnings from DuPont

  1. Serged and bound seams are degraded by some hazardous liquid chemicals, such as strong acids, and should not be worn when these chemicals are present.
  2. CAUTION: This information is based upon technical data that DuPont believes to be reliable. It is subject to revision as additional knowledge and experience are gained. DuPont makes no guarantee of results and assumes no obligation or liability...
    ... in connection with this information. It is the user's responsibility to determine the level of toxicity and the proper personal protective equipment needed. The information set forth herein reflects laboratory performance of fabrics, not complete garments, under controlled conditions. It is intended for informational use by persons having technical skill for evaluation under their specific end-use conditions, at their own discretion and risk. Anyone intending to use this information should first verify that the garment selected is suitable for the intended use. In many cases, seams and closures have shorter breakthrough times and higher permeation rates than the fabric. Please contact DuPont for specific data. If fabric becomes torn, abraded or punctured, or if seams or closures fail, or if attached gloves, visors, etc. are damaged, end user should discontinue use of garment to avoid potential exposure to chemical. Since conditions of use are outside our control, we make no warranties, express or implied, including, without limitation, no warranties of merchantability or fitness for a particular use and assume no liability in connection with any use of this information. This information is not intended as a license to operate under or a recommendation to infringe any patent or technical information of DuPont or others covering any material or its use.

(DuPont, 2016)

First Aid
Warning: Highly toxic when inhaled or absorbed through the skin or the eyes. Potent cholinesterase inhibitor. Effects may be delayed. Caution is advised.

Signs and Symptoms of Tabun Exposure: Acute exposure to tabun may include headache, dizziness, muscle spasms, twitching, weakness, agitation, confusion, delirium, seizures, CNS depression, and coma. Miosis (contraction of the pupil), blurred vision, lacrimation, tachycardia (rapid heart beat) or bradycardia (slow heart beat), hypertension or hypotension, and chest pain also are common. Respiratory effects include bronchospasm, bronchial secretions, dyspnea (difficult or labored breathing), rales (abnormal respiratory sound), respiratory depression and respiratory paralysis. Gastrointestinal effects include salivation, vomiting, diarrhea, and abdominal pain.

Emergency Life-Support Procedures: Acute exposure to tabun may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.

Inhalation Exposure:
1. Move victims to fresh air. Emergency personnel should avoid self-exposure to tabun.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
4. Rush to a health care facility.

Dermal/Eye Exposure:
1. Remove victims from exposure. Emergency personnel should avoid self-exposure to tabun.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
3. Remove contaminated clothing and shoes as soon as possible. Speed in removing material from skin is of extreme importance.
4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.
5. Wash exposed skin areas thoroughly with soap and water. Speed in removing material from skin is of extreme importance.
6. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
7. Rush to a health care facility.

Ingestion Exposure:
1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
2. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
3. DO NOT induce vomiting.
4. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water.
5. Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims. Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults.
6. Rush to a health care facility. (EPA, 1998)

Physical Properties

The Physical Property fields include properties such as vapor pressure and boiling point, as well as explosive limits and toxic exposure thresholds. The information in CAMEO Chemicals comes from a variety of data sources.
Chemical Formula:
  • C5H11N2O2P
Flash Point: 172 ° F (EPA, 1998)
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: -58 ° F (EPA, 1998)
Vapor Pressure: 0.07 mm Hg at 77 ° F (EPA, 1998)
Vapor Density (Relative to Air): 5.63 (EPA, 1998)
Specific Gravity: 1.073 (EPA, 1998)
Boiling Point: 464 ° F at 760 mm Hg (EPA, 1998)
Molecular Weight: 162.15 (EPA, 1998)
Water Solubility: data unavailable
Ionization Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

Final AEGLs for Agent GA (Tabun) (77-81-6)
Exposure Period AEGL-1 AEGL-2 AEGL-3
10 minutes 0.001 ppm 0.013 ppm 0.11 ppm
30 minutes 0.0006 ppm 0.0075 ppm 0.057 ppm
60 minutes 0.00042 ppm 0.0053 ppm 0.039 ppm
4 hours 0.00021 ppm 0.0026 ppm 0.021 ppm
8 hours 0.00015 ppm 0.002 ppm 0.015 ppm
(NAC/NRC, 2016)

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Nerve Agent GA; (Tabun, Ethyl dimethylamido-cyanophosphate) (77-81-6) 0.00042 ppm 0.0053 ppm 0.039 ppm
(DOE, 2016)

Regulatory Information

The Regulatory Information fields include information from the U.S. Environmental Protection Agency's Title III Consolidated List of Lists and the U.S. Department of Homeland Security's Chemical Facility Anti-Terrorism Standards (see more about these data sources).

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
Tabun 77-81-6 10 pounds 10 pounds

(EPA List of Lists, 2015)

DHS Chemical Facility Anti-Terrorism Standards (CFATS)

RELEASE THEFT SABOTAGE
Chemical of Interest CAS Number Min Conc STQ Security
Issue
Min Conc STQ Security
Issue
Min Conc STQ Security
Issue
Tabun; [o-Ethyl-N,N-dimethylphosphoramido-cyanidate] 77-81-6 CUM 100 grams CW/CWP

(DHS, 2007)

Alternate Chemical Names

This section provides a listing of alternate names for this chemical, including trade names and synonyms.