Chemical Datasheet
BROMOTRIFLUOROETHYLENE |
|
Chemical Identifiers
![](javascript:dropDownText("sec1_help","sec1_help_marker","/images/dropdown_opened.gif","/images/dropdown_closed.gif"))
The
Chemical Identifier fields
include common identification numbers, the
NFPA diamond,
U.S. Department of Transportation hazard labels, and a general
description of the chemical. The information in CAMEO Chemicals comes
from a variety of
data sources.
| CAS Number | UN/NA Number | DOT Hazard Label | USCG CHRIS Code |
|---|---|---|---|
|
|
none |
NFPA 704
data unavailable
| NIOSH Pocket Guide | International Chem Safety Card |
|---|---|
| none | none |
General Description
A colorless gas (boiling point -2 to 0°C) shipped in cylinders or, if polymerized, a liquid. Heating the containers of gas may cause them to rupture violently and rocket. Polymeric bromotrifluoroethylene is a clear oily liquid of widely variable viscosity and density.
Hazards
![](javascript:dropDownText("sec2_help","sec2_help_marker","/images/dropdown_opened.gif","/images/dropdown_closed.gif"))
The
Hazard fields
include
special hazard alerts,
air and water
reactions, fire hazards, health hazards, a reactivity profile, and
details about
reactive groups assignments
and
potentially incompatible absorbents.
The information in CAMEO Chemicals comes from a variety of
data sources.
Reactivity Alerts
- Highly Flammable
- Polymerizable
Air & Water Reactions
Highly flammable (gas).
Fire Hazard
Excerpt from ERG Guide 116 [Gases - Flammable (Unstable)]:
EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Silane (UN2203) will ignite spontaneously in air. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket. (ERG, 2016)
EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Silane (UN2203) will ignite spontaneously in air. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket. (ERG, 2016)
Health Hazard
Excerpt from ERG Guide 116 [Gases - Flammable (Unstable)]:
Vapors may cause dizziness or asphyxiation without warning. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases. (ERG, 2016)
Vapors may cause dizziness or asphyxiation without warning. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases. (ERG, 2016)
Reactivity Profile
Reactivity often inhibited by adding tributylamine [Lancaster].
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below. More info about absorbents, including situations to watch out for...
- Mineral-Based & Clay-Based Absorbents
- Dirt/Earth
Response Recommendations
![](javascript:dropDownText("sec3_help","sec3_help_marker","/images/dropdown_opened.gif","/images/dropdown_closed.gif"))
The
Response Recommendation fields
include isolation and evacuation distances, as well as recommendations for
firefighting, non-fire response, protective clothing, and first aid. The
information in CAMEO Chemicals comes from a variety of
data sources.
Isolation and Evacuation
Excerpt from ERG Guide 116 [Gases - Flammable (Unstable)]:
As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 800 meters (1/2 mile).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. (ERG, 2016)
As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 800 meters (1/2 mile).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. (ERG, 2016)
Firefighting
Excerpt from ERG Guide 116 [Gases - Flammable (Unstable)]:
DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
SMALL FIRE: Dry chemical or CO2.
LARGE FIRE: Water spray or fog. Move containers from fire area if you can do it without risk.
FIRE INVOLVING TANKS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)
DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
SMALL FIRE: Dry chemical or CO2.
LARGE FIRE: Water spray or fog. Move containers from fire area if you can do it without risk.
FIRE INVOLVING TANKS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)
Non-Fire Response
Excerpt from ERG Guide 116 [Gases - Flammable (Unstable)]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. Do not touch or walk through spilled material. Do not direct water at spill or source of leak. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Isolate area until gas has dispersed. (ERG, 2016)
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. Do not touch or walk through spilled material. Do not direct water at spill or source of leak. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Isolate area until gas has dispersed. (ERG, 2016)
Protective Clothing
Excerpt from ERG Guide 116 [Gases - Flammable (Unstable)]:
Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)
Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Excerpt from ERG Guide 116 [Gases - Flammable (Unstable)]:
Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Keep victim calm and warm. (ERG, 2016)
Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Keep victim calm and warm. (ERG, 2016)
Physical Properties
![](javascript:dropDownText("sec4_help","sec4_help_marker","/images/dropdown_opened.gif","/images/dropdown_closed.gif"))
The
Physical Property fields
include properties such as vapor pressure and
boiling point, as well as explosive limits and
toxic exposure thresholds.
The information in CAMEO Chemicals comes from a variety of
data sources.
| Chemical Formula: |
|
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight:
160.921
Water Solubility: data unavailable
Ionization Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.PACs (Protective Action Criteria)
| Chemical | PAC-1 | PAC-2 | PAC-3 |
|---|---|---|---|
| Bromotrifluoroethylene (598-73-2) | 3.2 ppm | 230 ppm | 1400 ppm |
(DOE, 2016)
Regulatory Information
![](javascript:dropDownText("sec5_help","sec5_help_marker","/images/dropdown_opened.gif","/images/dropdown_closed.gif"))
The
Regulatory Information fields
include information from the U.S. Environmental Protection Agency's Title
III Consolidated List of Lists and the U.S. Department of Homeland
Security's Chemical Facility Anti-Terrorism Standards (see more about these
data sources).
EPA Consolidated List of Lists
| Regulatory Name | CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ | EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
|---|---|---|---|---|---|---|---|
| Bromotrifluoroethylene | 598-73-2 | 10000 pounds | |||||
| Ethene, bromotrifluoro- | 598-73-2 | 10000 pounds |
(EPA List of Lists, 2015)
DHS Chemical Facility Anti-Terrorism Standards (CFATS)
| RELEASE | THEFT | SABOTAGE | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Chemical of Interest | CAS Number | Min Conc | STQ | Security Issue |
Min Conc | STQ | Security Issue |
Min Conc | STQ | Security Issue |
| Bromotrifluorethylene; [Ethene, bromotrifluoro-] | 598-73-2 | 1.00 % | 10000 pounds | flammable | ||||||
(DHS, 2007)
Alternate Chemical Names
![](javascript:dropDownText("sec6_help","sec6_help_marker","/images/dropdown_opened.gif","/images/dropdown_closed.gif"))
This section provides a listing of alternate names for this chemical,
including trade names and synonyms.
- 1-BROMO-1,2,2-TRIFLUOROETHYLENE
- BROMOTRIFLUOROETHENE
- BROMOTRIFLUOROETHYLENE
- ETHENE, BROMOTRIFLUORO-
- ETHYLENE, BROMOTRIFLUORO-
- 1,2,2-TRIFLUORO-2-BROMOETHYLENE
- TRIFLUOROBROMOETHYLENE
- TRIFLUOROVINYL BROMIDE
Web site owner:
Office of Response and Restoration
,
National Ocean Service,
National Oceanic and Atmospheric Administration.
USA.gov.
CAMEO Chemicals version 2.7 rev 2.