Chemical Datasheet
AMMONIUM OXALATE |
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Chemical Identifiers
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Chemical Identifier fields
include common identification numbers, the
NFPA diamond
U.S. Department of Transportation hazard labels, and a general
description of the chemical. The information in CAMEO Chemicals comes
from a variety of
data sources.
| CAS Number | UN/NA Number | DOT Hazard Label | USCG CHRIS Code |
|---|---|---|---|
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| NIOSH Pocket Guide | International Chem Safety Card | ||
| none | |||
NFPA 704
data unavailable
General Description
Odorless solid. Sinks and mixes slowly with water. (USCG, 1999)
Hazards
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The
Hazard fields
include
special hazard alerts
air and water
reactions, fire hazards, health hazards, a reactivity profile, and
details about
reactive groups assignments
and
potentially incompatible absorbents.
The information in CAMEO Chemicals comes from a variety of
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Reactivity Alerts
none
Air & Water Reactions
Water soluble.
Fire Hazard
Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fire. (USCG, 1999)
Health Hazard
Ingestion or excessive inhalation of dust causes systemic poisoning; possible symptoms include pain in throat, esophagus, and stomach; mucous membranes turn white; vomiting, severe purging, weak pulse, cardiovascular collapse, neuromuscular symptoms. Contact with eyes causes irritation. Contact with skin causes irritation or severe burns. (USCG, 1999)
Reactivity Profile
AMMONIUM OXALATE can act as a reducing agent in reactions that generate carbon dioxide. Reacts within a few seconds with solutions of sodium hypochlorite [Mellor 2 Supp. 1:550 1956].
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
No information available.
Response Recommendations
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The
Response Recommendation fields
include isolation and evacuation distances, as well as recommendations for
firefighting, non-fire response, protective clothing, and first aid. The
information in CAMEO Chemicals comes from a variety of
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Isolation and Evacuation
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Fire Extinguishing Agents: Water, foam (USCG, 1999)
Non-Fire Response
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2020)
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2020)
Protective Clothing
Approved dust respirator; rubber or plastic-coated gloves; chemical goggles (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Speed is essential.
INHALATION: remove to fresh air.
INGESTION: call physician immediately; induce vomiting.
EYES: flush with water and seek medical attention.
SKIN: flush with water.
OTHER: watch for swelling of the glottis and delayed constriction of the esophagus. (USCG, 1999)
INHALATION: remove to fresh air.
INGESTION: call physician immediately; induce vomiting.
EYES: flush with water and seek medical attention.
SKIN: flush with water.
OTHER: watch for swelling of the glottis and delayed constriction of the esophagus. (USCG, 1999)
Physical Properties
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The
Physical Property fields
include properties such as vapor pressure and
boiling point, as well as explosive limits and
toxic exposure thresholds
The information in CAMEO Chemicals comes from a variety of
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Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
| Chemical Formula: |
|
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
1.5
at 65.3°F
(USCG, 1999)
- Denser than water; will sink
Boiling Point: data unavailable
Molecular Weight:
142.11
(USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.PACs (Protective Action Criteria)
| Chemical | PAC-1 | PAC-2 | PAC-3 |
|---|---|---|---|
| Diammonium oxalate; (Ethanedioic acid, diammonium salt) (1113-38-8) | 30 mg/m3 | 330 mg/m3 | 2000 mg/m3 |
| Ammonium oxalate monohydrate (5972-73-6) | 30 mg/m3 | 330 mg/m3 | 2000 mg/m3 |
| Ammonium oxalate; (Diammonium oxalate monohydrate) (6009-70-7) | 30 mg/m3 | 330 mg/m3 | 2000 mg/m3 |
(DOE, 2018)
Regulatory Information
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The
Regulatory Information fields
include information from
the U.S. Environmental Protection Agency's Title III Consolidated List of
Lists,
the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility
Anti-Terrorism Standards,
and the U.S. Occupational Safety and Health Administration's
Process Safety Management of Highly Hazardous Chemicals Standard List
(see more about these
data sources).
EPA Consolidated List of Lists
| Regulatory Name | CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ | EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
|---|---|---|---|---|---|---|---|
| Ammonium oxalate | 14258-49-2 | 5000 pounds | |||||
| Ammonium oxalate | 5972-73-6 | 5000 pounds | |||||
| Ammonium oxalate | 6009-70-7 | 5000 pounds |
(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.OSHA Process Safety Management (PSM) Standard List
No regulatory information available.Alternate Chemical Names
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This section provides a listing of alternate names for this chemical,
including trade names and synonyms.
- AMMONIUM OXALATE
- AMMONIUM OXALATE ((NH4)2C2O4) MONOHYDRATE
- AMMONIUM OXALATE HYDRATE
- AMMONIUM OXALATE MONOHYDRATE
- DIAMMONIUM OXALATE
- DIAMMONIUM OXALATE MONOHYDRATE
- OXALIC ACID, DIAMMONIUM SALT
- OXALIC ACID, DIAMMONIUM SALT, MONOHYDRATE
Web site owner:
Office of Response and Restoration
,
National Ocean Service,
National Oceanic and Atmospheric Administration.
USA.gov.
CAMEO Chemicals version 3.0.0.