Chemical Datasheet
NITROGLYCERIN, DESENSITIZED, [LIQUID] |
|
Chemical Identifiers
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The
Chemical Identifier fields
include common identification numbers, the
NFPA diamond
U.S. Department of Transportation hazard labels, and a general
description of the chemical. The information in CAMEO Chemicals comes
from a variety of
data sources.
| CAS Number | UN/NA Number | DOT Hazard Label | USCG CHRIS Code |
|---|---|---|---|
|
|
none | |
| NIOSH Pocket Guide | International Chem Safety Card | ||
Nitroglycerine
|
|||
NFPA 704
| Diamond | Hazard | Value | Description | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
Health
|
2 | Can cause temporary incapacitation or residual injury. | |||||||||
Flammability
|
3 | Can be ignited under almost all ambient temperature conditions. | ||||||||||
Instability
|
4 | Readily capable of detonation or explosive decomposition or explosive reaction at normal temperatures and pressures. | ||||||||||
Special
|
Note: NFPA ratings shown are for nitroglycerin, CAS number 55-63-0.
(NFPA, 2010)
General Description
A pale yellow, viscous liquid that is slightly soluble in water and more dense than water. Sensitive to shock and heat. May explode under prolonged exposure to fire or heat. Primary hazard is the blast of an instantaneous explosion and not flying fragment or projectiles. Used medicinally.
Hazards
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The
Hazard fields
include
special hazard alerts
air and water
reactions, fire hazards, health hazards, a reactivity profile, and
details about
reactive groups assignments
and
potentially incompatible absorbents.
The information in CAMEO Chemicals comes from a variety of
data sources.
Reactivity Alerts
- Highly Flammable
- Explosive
- Strong Oxidizing Agent
Air & Water Reactions
Highly flammable. Slightly soluble in water.
Fire Hazard
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]:
MAY EXPLODE AND THROW FRAGMENTS 1600 METERS (1 MILE) OR MORE IF FIRE REACHES CARGO. For information on "Compatibility Group" letters, refer to Glossary section. (ERG, 2016)
MAY EXPLODE AND THROW FRAGMENTS 1600 METERS (1 MILE) OR MORE IF FIRE REACHES CARGO. For information on "Compatibility Group" letters, refer to Glossary section. (ERG, 2016)
Health Hazard
Exposure Routes: inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms: Throbbing headache; dizziness; nausea, vomiting, abdominal pain; hypotension; flush; palpitations; methemoglobinemia; delirium, central nervous system depression; angina; skin irritation
Target Organs: cardiovascular system, blood, skin, central nervous system (NIOSH, 2016)
Symptoms: Throbbing headache; dizziness; nausea, vomiting, abdominal pain; hypotension; flush; palpitations; methemoglobinemia; delirium, central nervous system depression; angina; skin irritation
Target Organs: cardiovascular system, blood, skin, central nervous system (NIOSH, 2016)
Reactivity Profile
NITROGLYCERIN, DESENSITIZED, [LIQUID] is incompatible with ozone and acids, and is an OSHA Class A Explosive (1910.109) (NIOSH, 2016). Less subject to explosion when heated or shocked than ordinary nitroglycerin because of the addition of desensitizing materials, but still dangerous. May begin a vigorous reaction that culminates in a detonation if mixed with reducing agents, including hydrides, sulfides and nitrides. Reacts with inorganic bases to form explosive salts. Sensitized toward decomposition by the presence of metal oxides.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below. More info about absorbents, including situations to watch out for...
- Cellulose-Based Absorbents
- Expanded Polymeric Absorbents
Response Recommendations
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The
Response Recommendation fields
include isolation and evacuation distances, as well as recommendations for
firefighting, non-fire response, protective clothing, and first aid. The
information in CAMEO Chemicals comes from a variety of
data sources.
Isolation and Evacuation
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]:
Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions.
LARGE SPILL: Consider initial evacuation for 800 meters (1/2 mile) in all directions.
FIRE: If rail car or trailer is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2016)
Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions.
LARGE SPILL: Consider initial evacuation for 800 meters (1/2 mile) in all directions.
FIRE: If rail car or trailer is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2016)
Firefighting
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]:
CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed to heat.
TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe distance, with extinguisher ready for possible re-ignition. (ERG, 2016)
CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed to heat.
TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe distance, with extinguisher ready for possible re-ignition. (ERG, 2016)
Non-Fire Response
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 METERS (330 FEET) OF ELECTRIC DETONATORS. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2016)
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 METERS (330 FEET) OF ELECTRIC DETONATORS. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2016)
Protective Clothing
Skin: Wear appropriate personal protective clothing to prevent skin contact.
Eyes: Wear appropriate eye protection to prevent eye contact.
Wash skin: The worker should immediately wash the skin when it becomes contaminated.
Remove: Work clothing that becomes wet should be immediately removed due to its flammability hazard(i.e. for liquids with flash point < 100°F)
Change: Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premise.
Provide: Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2016)
Eyes: Wear appropriate eye protection to prevent eye contact.
Wash skin: The worker should immediately wash the skin when it becomes contaminated.
Remove: Work clothing that becomes wet should be immediately removed due to its flammability hazard(i.e. for liquids with flash point < 100°F)
Change: Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premise.
Provide: Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2016)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.
Skin: If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.
Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible.
Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2016)
Skin: If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.
Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible.
Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2016)
Physical Properties
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The
Physical Property fields
include properties such as vapor pressure and
boiling point, as well as explosive limits and
toxic exposure thresholds
The information in CAMEO Chemicals comes from a variety of
data sources.
| Chemical Formula: |
|
Flash Point:
Explodes
(NIOSH, 2016)
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point:
56 ° F
(NIOSH, 2016)
Vapor Pressure:
0.0003 mm Hg
(NIOSH, 2016)
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
1.6
(NIOSH, 2016)
Boiling Point:
Begins to decompose at 122-140° F
(NIOSH, 2016)
Molecular Weight:
227.1
(NIOSH, 2016)
Water Solubility:
0.1 %
(NIOSH, 2016)
Ionization Potential: data unavailable
IDLH:
75 mg/m3
(as nitroglycerine)
(NIOSH, 2016)
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.PACs (Protective Action Criteria)
| Chemical | PAC-1 | PAC-2 | PAC-3 |
|---|---|---|---|
| Nitroglycerin (55-63-0) | 0.1 mg/m3 | 2 mg/m3 | 75 mg/m3 |
(DOE, 2016)
Regulatory Information
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The
Regulatory Information fields
include information from
the U.S. Environmental Protection Agency's Title III Consolidated List of
Lists,
the U.S. Department of Homeland Security's Chemical Facility
Anti-Terrorism Standards,
and the U.S. Occupational Safety and Health Administration's
Process Safety Management of Highly Hazardous Chemicals Standard List
(see more about these
data sources).
EPA Consolidated List of Lists
| Regulatory Name | CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ | EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
|---|---|---|---|---|---|---|---|
| Nitroglycerin | 55-63-0 | 10 pounds | 313 | P081 |
(EPA List of Lists, 2015)
DHS Chemical Facility Anti-Terrorism Standards (CFATS)
| RELEASE | THEFT | SABOTAGE | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Chemical of Interest | CAS Number | Min Conc | STQ | Security Issue |
Min Conc | STQ | Security Issue |
Min Conc | STQ | Security Issue |
| Nitroglycerine | 55-63-0 | ACG | 5000 pounds | explosive | ACG | 400 pounds | EXP/IEDP | |||
- ACG = a commercial grade.
- EXP/IEDP = explosives/improvised explosive device precursors.
(DHS, 2007)
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.Alternate Chemical Names
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This section provides a listing of alternate names for this chemical,
including trade names and synonyms.
- ANGIBID
- ANGININE
- ANGIOLINGUAL
- ANGORIN
- BLASTING OIL
- CARDAMIST
- CHITAMITE
- GILUCOR NITRO
- GLONOIN
- GLYCERIN TRINITRATE
- GLYCEROL TRINITRATE
- GLYCERYL NITRATE
- GLYCERYL TRINITRATE
- GTN
- KLAVIKORDAL
- LENITRAL
- MYOGLYCERIN
- NG
- NIGLIN
- NIGLYCON
- NITORA
- NITRIN
- NITRINE
- NITRINE-TDC
- NITRO-DUR
- NITRO-LENT
- NITRO-SPAN
- NITRODERM
- NITROGLYCERIN
- NITROGLYCERIN, DESENSITIZED, [LIQUID]
- NITROGLYCERINE
- NITROGLYCEROL
- NITROGLYN
- NITROL
- NITROL (PHARMACEUTICAL)
- NITROLAN
- NITROLETTEN
- NITROLINGUAL
- NITROLOWE
- NITROMEL
- NITRONG
- NITROPERCUTEN
- NITRORECTAL
- NITRORETARD
- NITROSTABILIN
- NITROSTAT
- NITROZELL RETARD
- NK 843
- NTG
- NYSCONITRINE
- PENOBEL 2
- PERGLOTTAL
- PERLINGANIT
- PROPANETRIOL TRINITRATE
- 1,2,3-PROPANETRIOL TRINITRATE
- 1,2,3-PROPANETRIYL NITRATE
- S.N.G.
- SOUP
- TEMPONITRIN
- TRINALGON
- TRINITRIN
- TRINITROGLYCERIN
- TRINITROGLYCERINE
- TRINITROGLYCEROL
- TRINITROL
- VASOGLYN
Web site owner:
Office of Response and Restoration,
National Ocean Service,
National Oceanic and Atmospheric Administration.
USA.gov.
CAMEO Chemicals version 2.7.1 rev 3.