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United Nations/North American Number Datasheet

UN/NA 3385

6.1 - Poison Inhalation Hazard 4.3 - Dangerous when wet

Emergency Response Guidebook (ERG, 2020)

A caution icon. The ERG recommendations are developed for use during the initial phase of transportation incidents; they are not intended for spills at facilities.

Material Names

  • Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A)
  • Toxic by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A)
ERG book cover

Response Guide 139

Substances - Water-Reactive (Emitting Flammable and Toxic Gases) Sustancias - Reactivas con el Agua (Emiten Gases Inflamables y Tóxicos) Substances - Réagissant à l'Eau (Émettant des Gaz Inflammables et Toxiques)

 

ERG Table 1: Initial Isolation and Protective Action Distances

Name of Material Small Spills
(from a small package or small leak)
Large Spills
(from a large package or many small packages)
First
Isolate
in all Directions
Then Protect Downwind First
Isolate
in all Directions
Then Protect Downwind
Day Night Day Night
Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 200 ft 0.4 mi 0.8 mi 600 ft 1.4 mi 2.6 mi
Toxic by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) 200 ft 0.4 mi 0.8 mi 600 ft 1.4 mi 2.6 mi

The ERG doesn't predict that large amounts of toxic-by-inhalation gases will be produced if this material is spilled in water.

Hazmat Table (49 CFR 172.101)

UN/NA Proper Shipping Name Hazard Class Labels Notes*

* There are three notes: (1) whether the displayed information is for domestic (U.S.) or international shipping (if neither is specifically indicated, it applies to both), (2) whether the proper shipping name must include one or more technical names of the hazardous material in parentheses, and (3) whether the hazardous material is an inhalation hazard.
UN Toxic by inhalation liquid, water-reactive, n.o.s. with an LC50 lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50 6.1 6.1, 4.3 Technical Name Required, Inhalation Hazard Zone A

  6.1 - Poison Inhalation Hazard

  4.3 - Dangerous when wet