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Chemical Datasheet
NICKEL BROMIDE |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
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NIOSH Pocket Guide |
International Chem Safety Card |
Nickel metal and other compounds (as Ni)
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none
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NFPA 704
data unavailable
General Description
Yellowish-green odorless solid. Sinks in and mixes with water. (USCG, 1999)
Hazards
Reactivity Alerts
none
Air & Water Reactions
Deliquescent. Soluble in water.
Fire Hazard
Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire. (USCG, 1999)
Health Hazard
Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin. (USCG, 1999)
Reactivity Profile
NICKEL BROMIDE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes it produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition it emits toxic bromide fumes. [M. K.]
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
No information available.
Response Recommendations
Isolation and Evacuation
Excerpt from 151
[Substances - Toxic (Non-Combustible)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from 151
[Substances - Toxic (Non-Combustible)]:
SMALL FIRE: Dry chemical, CO2 or water spray.
LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal. Avoid aiming straight or solid streams directly onto the product.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)
Non-Fire Response
Excerpt from 151
[Substances - Toxic (Non-Combustible)]:
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2020)
Protective Clothing
Bu. Mines approved respirator; rubber gloves; face shield or safety goggles; protective clothing. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
INHALATION: move to fresh air; get medical attention if exposure has been severe.
INGESTION: give large amounts of water.
EYES: flush with water for at least 15 min.
SKIN: wash with soap and water. (USCG, 1999)
Physical Properties
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
4
at 68°F
(est)
(USCG, 1999)
- Denser than water; will sink
Boiling Point: data unavailable
Molecular Weight:
272.6
(USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH:
10 mg Ni/m3
; A potential occupational carcinogen.
(NIOSH, 2023)
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Nickel(II) bromide (13462-88-9)
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1.1 mg/m3 |
12 mg/m3 |
73 mg/m3 |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
Nickel Compounds |
N495 |
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& |
313 |
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(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- NICKEL BROMIDE
- NICKEL BROMIDE TRIHYDRATE