2-METHYLPYRIDINE

Diamond	Hazard	Value	Description
3 3 0	Health	3	Can cause serious or permanent injury.
	Flammability	3	Can be ignited under almost all ambient temperature conditions.
	Instability	0	Normally stable, even under fire conditions.
	Special

Colorless liquid with a strong, unpleasant odor. Floats on water. Poisonous vapor is produced. (USCG, 1999)

• Highly Flammable

Highly flammable. Water soluble.

Special Hazards of Combustion Products: When heated to decompo- sition, emits toxic fumes of cyanide.

Behavior in Fire: Heat may cause pressure buildup in closed containers. Use water to keep container cool. (USCG, 1999)

INHALATION, INGESTION OR SKIN ABSORPTION: Narcosis, headache, nausea, giddiness, vomiting. EYES: Severe irritation. SKIN: Causes burns. INGESTION: Irritation and gastric upset. (USCG, 1999)

2-METHYLPYRIDINE is hygroscopic. This compound reacts with hydrogen peroxide, iron(II) sulfate, sulfuric acid, oxidizing agents, acids, and metals. (NTP, 1992)

• Amines, Phosphines, and Pyridines

Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below.

• Mineral-Based & Clay-Based Absorbents

Excerpt from 129 [Flammable Liquids (Water-Miscible / Noxious)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)

Fire Extinguishing Agents Not to Be Used: Water may be ineffective.

Fire Extinguishing Agents: Carbon dioxide, dry chemical or "alcohol" foam. (USCG, 1999)

Neutralizing Agents for Acids and Caustics: Flush with water (USCG, 1999)

Wear goggles, rubber gloves, self-contained breathing apparatus and protective overclothing. (USCG, 1999)

Normalized Breakthrough Times (in Minutes)

Chemical	CAS Number	State	QS	QC	SL	C3	TF	TP	RC	TK	RF
Methyl pyridine, 2-	109-06-8	Liquid				>480	>480	>480	>480	>480	>480
Picoline, 2-	109-06-8	Liquid				>480	>480	>480	>480	>480	>480

Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

(DuPont, 2023)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

• ALPHA-METHYLPYRIDINE
• ALPHA-PICOLINE
• 2-METHYLPYRIDINE
• O-METHYLPYRIDINE
• O-PICOLINE
• PICOLINE
• 2-PICOLINE
• PYRIDINE, 2-METHYL-
• RRCA WASTE NUMBER U191