Print
Chemical Datasheet

HEXADECYLTRIMETHYLAMMONIUM CHLORIDE

9 - Miscellaneous hazardous material

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 112-02-7
  • 3082
  • Class 9
  • HAC
NIOSH Pocket Guide International Chem Safety Card
none none
NFPA 704
data unavailable
General Description
Colorless to pale yellow liquid with an odor of rubbing alcohol. Floats or sinks in water. (USCG, 1999)

Hazards

Reactivity Alerts
none
Air & Water Reactions
No rapid reaction with air. No rapid reaction with water.
Fire Hazard
Special Hazards of Combustion Products: Irritating fumes of hydrogen chloride may form in fires.

Behavior in Fire: Solvent vapors are heavier than air and may travel to a source of ignition and flash back. (USCG, 1999)
Health Hazard
Ingestion may produce toxic effects. Contact with eyes or skin may cause severe damage. (USCG, 1999)
Reactivity Profile
HEXADECYLTRIMETHYLAMMONIUM CHLORIDE is a quaternary ammonium compound. Therefore it has a permanently charged nitrogen atom with four alkyl or aryl groups on it. Compounds in this group are generally soluble in water and are near pH 7 (neutral). They do not undergo the acid-base reactions typical of primary, secondary, or tertiary ammonium ions.

Quaternary ammonium salts often serve as catalysts in reactions. They are incompatible with many strong oxidizers and reducing agents, such as metal hydrides, alkali/active metals, and organometallics.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

Response Recommendations

Isolation and Evacuation
Excerpt from 171 Polymerizable warning [Substances (Low to Moderate Hazard)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Fire Extinguishing Agents Not to Be Used: Water may be ineffective

Fire Extinguishing Agents: Dry chemical, alcohol foam, carbon dioxide (USCG, 1999)
Non-Fire Response
Excerpt from 171 Polymerizable warning [Substances (Low to Moderate Hazard)]:

Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. For Asbestos, avoid inhalation of dust. Cover spill with plastic sheet or tarp to minimize spreading. Do not clean up or dispose of, except under supervision of a specialist.

SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.

SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later disposal.

LARGE SPILL: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2020)
Protective Clothing
Goggles or face shield; rubber gloves (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
INGESTION: do NOT induce vomiting; drink large quanities of fluid and call a physician immediately.

EYES: flush with water for at least 15 min. and call a physician.

SKIN: flush with water. (USCG, 1999)

Physical Properties

Chemical Formula:
  • C19H42N.Cl
Flash Point: 69°F (USCG, 1999)
Lower Explosive Limit (LEL): 2 % (isopropyl alcohol) (USCG, 1999)
Upper Explosive Limit (UEL): 12 % (isopropyl alcohol) (USCG, 1999)
Autoignition Temperature: 750°F (USCG, 1999)
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: 0.9 at 77°F (approx.) (USCG, 1999) - Less dense than water; will float
Boiling Point: 180°F at 760 mmHg (isopropyl alcohol) (USCG, 1999)
Molecular Weight: 319 (solute only) (USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Hexadecyltrimethylammonium chloride (112-02-7) 1.1 mg/m3 12 mg/m3 70 mg/m3
(DOE, 2018)

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names