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Chemical Datasheet
GLUTARALDEHYDE SOLUTION |
|
Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 111-30-8
|
|
|
|
NIOSH Pocket Guide |
International Chem Safety Card |
Glutaraldehyde
|
- GLUTARALDEHYDE
- GLUTARALDEHYDE (50% SOLUTION)
|
NFPA 704
data unavailable
General Description
Light yellow liquid. Mixes with water. (USCG, 1999)
Hazards
Reactivity Alerts
- Polymerizable
- Water-Reactive
Air & Water Reactions
Polymerizes in the presence of water. (NTP, 1992)
Fire Hazard
Literature sources indicate that this chemical is nonflammable. (NTP, 1992)
Health Hazard
Contact with liquid causes severe irritation of eyes and irritation of skin. Chemical readily penetrates skin in harmful amounts. Ingestion causes irritation of mouth and stomach. (USCG, 1999)
Reactivity Profile
GLUTARALDEHYDE may discolor on exposure to air. It polymerizes on heating. This chemical is incompatible with strong oxidizing agents. It polymerizes in the presence of water. (NTP, 1992)
Belongs to the Following Reactive Group(s)
- Aldehydes
- Polymerizable Compounds
- Water and Aqueous Solutions
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been
known to react with the
absorbents
listed below.
- Cellulose-Based Absorbents
- Mineral-Based & Clay-Based Absorbents
- Dirt/Earth
Response Recommendations
Isolation and Evacuation
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)
Protective Clothing
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)
DuPont Tychem® Suit Fabrics
Normalized Breakthrough Times (in Minutes)
Chemical |
CAS Number |
State |
QS |
QC |
SL |
C3 |
TF |
TP |
RC |
TK |
RF |
Glutaral (5%) |
111-30-8 |
Liquid |
|
>480 |
|
|
|
|
>480 |
>480 |
>480 |
Glutaral (50%) |
111-30-8 |
Liquid |
|
|
>480 |
|
170 |
170 |
>480 |
>480 |
>480 |
Glutaraldehyde (5%) |
111-30-8 |
Liquid |
|
>480 |
|
|
|
|
>480 |
>480 |
>480 |
Glutaraldehyde (50%) |
111-30-8 |
Liquid |
|
|
>480 |
|
170 |
170 |
>480 |
>480 |
>480 |
Pentanedial, 1,5- (5%) |
111-30-8 |
Liquid |
|
>480 |
|
|
|
|
>480 |
>480 |
>480 |
Pentanedial, 1,5- (50%) |
111-30-8 |
Liquid |
|
|
>480 |
|
170 |
170 |
>480 |
>480 |
>480 |
Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be
used around heat, flames, sparks or in potentially flammable or
explosive environments. Only...
(DuPont, 2024)
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Physical Properties
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point:
less than 20°F
(USCG, 1999)
Vapor Pressure:
17 mmHg
at 68°F
(NTP, 1992)
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
1.062 to 1.124
at 68°F
(USCG, 1999)
Boiling Point:
369 to 372°F
at 760 mmHg
(decomposes)
(NTP, 1992)
Molecular Weight:
100.13
(NTP, 1992)
Water Solubility:
greater than or equal to 100 mg/mL
at 72°F
(NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
Chemical |
ERPG-1 |
ERPG-2 |
ERPG-3 |
Glutaraldehyde (111-30-8)
|
0.2 ppm |
1 ppm |
5 ppm |
(AIHA, 2022)
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Gluteraldehyde (111-30-8)
|
0.2 ppm |
1 ppm |
5 ppm |
(DOE, 2024)
Regulatory Information
EPA Consolidated List of Lists
No regulatory information available.
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- ALDESAN
- BACTRON K 31
- BANICIDE
- BIOMATE 743
- CIDEX
- CIDEX 7
- CIDEX-DIALYZER
- CLEANCIDE 275
- DIGLUTARIC ALDEHYDE
- FLOPERM 665X1
- GLUTACLEAN
- GLUTARAL
- GLUTARALDEHYDE
- GLUTARALDEHYDE SOLUTION
- GLUTARDIALDEHYDE
- GLUTAREX 28
- GLUTARIC ACID DIALDEHYDE
- GLUTARIC DIALDEHYDE
- GLUTOHYDE
- HOSPEX
- NCI-C55425
- PANAVIROCIDE
- 1,5-PENTANEDIAL
- 1,5-PENTANEDIONE
- POTENTIATED ACID GLUTARALDEHYDE
- RELUGAN GT
- RELUGAN GT 50
- RELUGAN GTW
- SONACIDE
- SPORICIDIN
- STERIHYDE
- STERIHYDE L
- TRET-O-LITE XC 102
- UCARCIDE 250