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Chemical Datasheet

ETHYLENE GLYCOL

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 107-21-1
none data unavailable
  • EGL
NIOSH Pocket Guide International Chem Safety Card
Ethylene glycol
  • ETHYLENE GLYCOL
NFPA 704
Diamond Hazard Value Description
1
2 0
Blue Health 2 Can cause temporary incapacitation or residual injury.
Red Flammability 1 Must be preheated before ignition can occur.
Yellow Instability 0 Normally stable, even under fire conditions.
White Special
(NFPA, 2010)
General Description
Ethylene glycol is a clear, colorless syrupy liquid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Since it is a liquid it can easily penetrate the soil and contaminate groundwater and nearby streams.

Hazards

Reactivity Alerts
none
Air & Water Reactions
No rapid reaction with air. No rapid reaction with water.
Fire Hazard
This chemical is combustible. (NTP, 1992)
Health Hazard
Inhalation of vapor is not hazardous. Ingestion causes stupor or coma, sometimes leading to fatal kidney injury. (USCG, 1999)
Reactivity Profile
Mixing ETHYLENE GLYCOL in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, oleum, sulfuric acid, [NFPA 1991].
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below.

Response Recommendations

Isolation and Evacuation
No information available.
Firefighting
No information available.
Non-Fire Response
No information available.
Protective Clothing
Excerpt from NIOSH Pocket Guide for Ethylene glycol:

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.

Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: DAILY - Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. (NIOSH, 2023)
DuPont Tychem® Suit Fabrics
Normalized Breakthrough Times (in Minutes)
Chemical CAS Number State QS QC SL C3 TF TP RC TK RF
Ethane 1,2-diol 107-21-1 Liquid >480 >480 >480 >480 >480 >480 >480
Ethylene glycol 107-21-1 Liquid >480 >480 >480 >480 >480 >480 >480
Glycol alcohol 107-21-1 Liquid >480 >480 >480 >480 >480 >480 >480
> indicates greater than.

Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

(DuPont, 2023)

First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Physical Properties

Chemical Formula:
  • C2H6O2
Flash Point: 232°F (NTP, 1992)
Lower Explosive Limit (LEL): 3.2 % (NTP, 1992)
Upper Explosive Limit (UEL): not listed (USCG, 1999)
Autoignition Temperature: 775°F (USCG, 1999)
Melting Point: 9°F (NTP, 1992)
Vapor Pressure: 0.06 mmHg at 68°F ; 1 mmHg at 127.4°F (NTP, 1992)
Vapor Density (Relative to Air): 2.14 (NTP, 1992) - Heavier than air; will sink
Specific Gravity: 1.115 at 68°F (USCG, 1999) - Denser than water; will sink
Boiling Point: 387.7°F at 760 mmHg (NTP, 1992)
Molecular Weight: 62.07 (NTP, 1992)
Water Solubility: greater than or equal to 100 mg/mL at 63.5°F (NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Ethylene glycol (107-21-1) 30 ppm 150 ppm 900 ppm LEL = 32000 ppm
(DOE, 2018)

Regulatory Information

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
Ethylene glycol 107-21-1 5000 pounds 313

(EPA List of Lists, 2022)

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names