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Chemical Datasheet
Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
|
none
|
data unavailable
|
|
NIOSH Pocket Guide |
International Chem Safety Card |
Ethylene glycol
|
|
NFPA 704
General Description
Ethylene glycol is a clear, colorless syrupy liquid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Since it is a liquid it can easily penetrate the soil and contaminate groundwater and nearby streams.
Hazards
Reactivity Alerts
none
Air & Water Reactions
No rapid reaction with air. No rapid reaction with water.
Fire Hazard
This chemical is combustible. (NTP, 1992)
Health Hazard
Inhalation of vapor is not hazardous. Ingestion causes stupor or coma, sometimes leading to fatal kidney injury. (USCG, 1999)
Reactivity Profile
Mixing ETHYLENE GLYCOL in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, oleum, sulfuric acid, [NFPA 1991].
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been
known to react with the
absorbent
listed below.
- Cellulose-Based Absorbents
Response Recommendations
Isolation and Evacuation
No information available.
Firefighting
No information available.
Non-Fire Response
No information available.
Protective Clothing
Excerpt from NIOSH Pocket Guide for Ethylene glycol:
Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.
Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.
Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.
Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Change: DAILY - Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. (NIOSH, 2023)
DuPont Tychem® Suit Fabrics
Normalized Breakthrough Times (in Minutes)
Chemical |
CAS Number |
State |
QS |
QC |
SL |
C3 |
TF |
TP |
RC |
TK |
RF |
Ethane 1,2-diol |
107-21-1 |
Liquid |
|
>480 |
>480 |
|
>480 |
>480 |
>480 |
>480 |
>480 |
Ethylene glycol |
107-21-1 |
Liquid |
|
>480 |
>480 |
|
>480 |
>480 |
>480 |
>480 |
>480 |
Glycol alcohol |
107-21-1 |
Liquid |
|
>480 |
>480 |
|
>480 |
>480 |
>480 |
>480 |
>480 |
Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be
used around heat, flames, sparks or in potentially flammable or
explosive environments. Only...
(DuPont, 2023)
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Physical Properties
Flash Point:
232°F
(NTP, 1992)
Lower Explosive Limit (LEL):
3.2 %
(NTP, 1992)
Upper Explosive Limit (UEL):
not listed
(USCG, 1999)
Autoignition Temperature:
775°F
(USCG, 1999)
Melting Point:
9°F
(NTP, 1992)
Vapor Pressure:
0.06 mmHg
at 68°F
; 1 mmHg at 127.4°F
(NTP, 1992)
Vapor Density (Relative to Air):
2.14
(NTP, 1992)
- Heavier than air; will sink
Specific Gravity:
1.115
at 68°F
(USCG, 1999)
- Denser than water; will sink
Boiling Point:
387.7°F
at 760 mmHg
(NTP, 1992)
Molecular Weight:
62.07
(NTP, 1992)
Water Solubility:
greater than or equal to 100 mg/mL
at 63.5°F
(NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
|
Ethylene glycol (107-21-1)
|
30 ppm |
150 ppm |
900 ppm |
LEL = 32000 ppm |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
Ethylene glycol |
107-21-1 |
|
|
5000 pounds |
313 |
|
|
(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- 146AR
- 1,2-DIHYDROXYETHANE
- DOWTHERM SR 1
- 1,2-ETHANDIOL
- ETHANE-1,2-DIOL
- 1,2-ETHANEDIOL
- ETHYLENE ALCOHOL
- ETHYLENE DIHYDRATE
- ETHYLENE GLYCOL
- 1,2-ETHYLENE GLYCOL
- FRIDEX
- GLYCOL
- GLYCOL ALCOHOL
- 2-HYDROXYETHANOL
- LUTROL-9
- M.E.G.
- MACROGOL 400 BPC
- MONOETHYLENE GLYCOL
- NCI-C00920
- NORKOOL
- RAMP
- TESCOL
- UCAR 17
- ZEREX