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Chemical Datasheet

ETHYLENE CYANOHYDRIN

6.1 - Poison

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 109-78-4
  • 2810
  • Poison
  • ETC
NIOSH Pocket Guide International Chem Safety Card
none
  • ETHYLENE CYANOHYDRIN
NFPA 704
Diamond Hazard Value Description
1
1 2
Blue Health 1 Can cause significant irritation.
Red Flammability 1 Must be preheated before ignition can occur.
Yellow Instability 2 Readily undergoes violent chemical changes at elevated temperatures and pressures.
White Special
(NFPA, 2010)
General Description
Colorless to yellow-brown liquid with a weak odor. Sinks and mixes with water. (USCG, 1999)

Hazards

Reactivity Alerts
none
Air & Water Reactions
Water soluble. Reacts slowly with water and steam to emit highly toxic, flammable vapors.
Fire Hazard
Special Hazards of Combustion Products: Toxic gases are generated when heated.

Behavior in Fire: Decomposes, generating toxic gases (USCG, 1999)
Health Hazard
Liquid causes eye irritation. If swallowed, may cause severe kidney injury. (USCG, 1999)
Reactivity Profile
ETHYLENE CYANOHYDRIN reacts violently with mineral acids, amines and inorganic bases. It also reacts violently with chlorosulfonic acid, sulfuric acid, oleum and sodium hydroxide. It is incompatible with bases, oxidizing agents, moisture and heat. It is corrosive to mild steel. (NTP, 1992)
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below.

Response Recommendations

Isolation and Evacuation
Excerpt from 153 Polymerizable warning [Substances - Toxic and/or Corrosive (Combustible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Fire Extinguishing Agents Not to Be Used: Water or foam may cause frothing.

Fire Extinguishing Agents: Carbon dioxide or dry chemical for small fires; alcohol- type foam for large fires. (USCG, 1999)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

STORAGE PRECAUTIONS: You should store this chemical under refrigerated temperatures, and protect it from moisture. (NTP, 1992)
Protective Clothing
Air-supplied mask; plastic gloves; rubber clothing; vapor- proof goggles. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Physical Properties

Chemical Formula:
  • C3H5NO
Flash Point: greater than 265°F (NTP, 1992)
Lower Explosive Limit (LEL): 2.3 % (NTP, 1992)
Upper Explosive Limit (UEL): 12.1 % (NTP, 1992)
Autoignition Temperature: 922°F (USCG, 1999)
Melting Point: -51°F (NTP, 1992)
Vapor Pressure: 0.08 mmHg at 77°F ; 20 mmHg at 243°F (NTP, 1992)
Vapor Density (Relative to Air): 2.5 (NTP, 1992) - Heavier than air; will sink
Specific Gravity: 1.047 at 68°F (USCG, 1999) - Denser than water; will sink
Boiling Point: 442°F at 760 mmHg (slight decomposition) (NTP, 1992)
Molecular Weight: 71.08 (NTP, 1992)
Water Solubility: greater than or equal to 100 mg/mL at 68°F (NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

No PAC information available.

Regulatory Information

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
Cyanide Compounds N106 & 313

(EPA List of Lists, 2022)

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names