ETHYL PHOSPHONOTHIOIC DICHLORIDE, ANHYDROUS

A clear colorless liquid with a pungent odor. Burns, but may be difficult to ignite. Denser than water. Very toxic by inhalation. Corrosive to metals and tissue.

• Water-Reactive

Reacts with water to form hydrogen chloride(hydrochloric acid)

Combustible. POISONOUS GASES ARE PRODUCED IN FIRE. Oxides of sulfur, phosphorus; hydrogen chloride and phosgene. Contact with water applied to adjacent fires will produce irritating fumes of hydrogen chloride. (USCG, 1999)

GAS PRODUCED IN REACTION WITH WATER. POISONOUS IF INHALED. Irritating to eyes, nose and throat. LIQUID: Irritating to skin and eyes. Harmful if swallowed. (USCG, 1999)

An acid halide and organothiophosphate. Acid halides are water reactive; some are violently reactive. They are incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Organothiophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

• Sulfonates, Phosphonates, and Thiophosphonates, Organic
• Acyl Halides, Sulfonyl Halides, and Chloroformates

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

• Cellulose-Based Absorbents
• Mineral-Based & Clay-Based Absorbents
• Dirt/Earth

Excerpt from 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 2927 datasheet.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)

Excerpt from 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

SMALL FIRE: Dry chemical, CO2 or water spray.

LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2020)

Excerpt from 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2020)

Wear goggles and self-contained breathing apparatus. (USCG, 1999)

No information available.

INHALATION: remove victim from exposure; oxygen can be used for pulmonary symptoms with decongestants; enforce complete rest, because effects may be delayed 24 hours; similar to phosgene poisoning.

EYES: flush thoroughly with water and seek medical attention; apply Pontocaine drops (1/2%) and cortisone ointment (1%).

SKIN: wash thoroughly with soap and water.

INGESTION: give large amounts of water; induce vomiting; get medical attention; enforce rest for 24-36 hours. (USCG, 1999)

• DICHLORIDE
• DICHLOROETHYLPHOSPHINE SULFIDE
• ETHANEPHOSPHONOTHIONODICHLORIDIC ACID
• ETHANETHIOPHOSPHONODICHLORIDIC ACID
• ETHYL PHOSPHONOTHIOIC DICHLORIDE
• ETHYL PHOSPHONOTHIOIC DICHLORIDE, ANHYDROUS
• ETHYL PHOSPHONOTHIOIC DICHLORIDE, [ANHYDROUS]
• ETHYL PHOSPHONOTHIOYL DICHLORIDE
• ETHYL PHOSPHORODICHLORIDO-
• ETHYL THIONOPHOSPHORYL
• ETHYLPHOSPHONOTHIOIC DICHLORIDE
• ETHYLPHOSPHONOTHIONIC DICHLORIDE
• ETHYLTHIONOPHOSPHONYL DICHLORIDE
• ETHYLTHIOPHOSPHONIC ACID DICHLORIDE
• ETHYLTHIOPHOSPHONIC DICHLORIDE
• THIONATE