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Chemical Datasheet
CATECHOL |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
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NIOSH Pocket Guide |
International Chem Safety Card |
Catechol
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NFPA 704
General Description
Solid; white; odorless. Sinks and mixes with water. (USCG, 1999)
Hazards
Reactivity Alerts
none
Air & Water Reactions
Turns brown on exposure to air and light, especially when moist. Water soluble. Aqueous solutions soon turn brown on exposure to air and light.
Fire Hazard
Combustible. POISONOUS GASES MAY BE PRODUCED WHEN HEATED. May form toxic fumes at high temperatures. (USCG, 1999)
Health Hazard
DUST: Irritating to eyes, nose and throat. If inhaled will cause coughing or difficult breathing. SOLID: Will burn skin and eyes. Harmful if swallowed. (USCG, 1999)
Reactivity Profile
POISONOUS GASES MAY BE PRODUCED WHEN HEATED. CATECHOL may form toxic fumes at high temperatures. (USCG, 1999). This compound can react with acid chlorides, acid anhydrides, bases and oxidizing agents. It reacts violently on contact with concentrated nitric acid. It acts as a reducing agent (NTP, 1992).
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
No information available.
Response Recommendations
Isolation and Evacuation
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
Extinguish with dry chemicals, alcohol foam, or carbon dioxide. Water may be ineffective on fire. Cool exposed containers with water. (USCG, 1999)
Non-Fire Response
Avoid contact with solid and dust. Keep people away. Wear rubber overclothing (including gloves). Stop discharge if possible. Isolate and remove discharged material. Notify local health and pollution control agencies. (USCG, 1999)
Protective Clothing
Excerpt from NIOSH Pocket Guide for Catechol:
Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.
Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.
Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.
Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Change: DAILY - Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises.
Provide: EYEWASH - Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation involving the wearing of eye protection. (NIOSH, 2024)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. Phenols are very toxic poisons AND corrosive and irritating, so that inducing vomiting may make medical problems worse. IMMEDIATELY call a hospital or poison control center and locate activated charcoal, egg whites, or milk in case the medical advisor recommends administering one of them. If advice from a physician is not readily available and the victim is conscious and not convulsing, give the victim a glass of activated charcoal slurry in water or, if this is not available, a glass of milk, or beaten egg whites and IMMEDIATELY transport victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, assure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Physical Properties
Flash Point:
261°F
(NTP, 1992)
Lower Explosive Limit (LEL):
Not Applicable. Combustible solid.
(USCG, 1999)
Upper Explosive Limit (UEL):
Not Applicable. Combustible solid
(USCG, 1999)
Autoignition Temperature: data unavailable
Melting Point:
221°F
(NTP, 1992)
Vapor Pressure:
5 mmHg
at 219°F
; 10 mmHg at 244.9°F
(NTP, 1992)
Vapor Density (Relative to Air):
3.79
(NTP, 1992)
- Heavier than air; will sink
Specific Gravity:
1.344
at 68°F
(USCG, 1999)
- Denser than water; will sink
Boiling Point:
473°F
at 760 mmHg
(sublimes)
(NTP, 1992)
Molecular Weight:
110.11
(NTP, 1992)
Water Solubility:
greater than or equal to 100 mg/mL
at 70.7°F
(NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Catechol (120-80-9)
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15 ppm |
96 ppm |
570 ppm |
(DOE, 2024)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
Catechol |
120-80-9 |
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100 pounds |
313 |
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(EPA List of Lists, 2024)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- 1, 2-BENZENEDIOL
- 1,2-BENZENEDIOL
- C.I. 76500
- C.I. OXIDATION BASE 26
- CATECHIN
- CATECHIN (PHENOL)
- CATECHOL
- CATECHOL (PHENOL)
- CW-C 2
- 1, 2-DIHYDROXYBENZENE
- 1,2-DIHYDROXYBENZENE
- DURAFUR DEVELOPER C
- FOURAMINE PCH
- FOURRINE 68
- 2-HYDROXYPHENOL
- O-BENZENEDIOL
- O-DIHYDROXYBENZENE
- O-DIOXYBENZENE
- O-DIPHENOL
- O-HYDROQUINONE
- O-HYDROXYPHENOL
- O-PHENYLENEDIOL
- OXYPHENIC ACID
- PELAGOL GREY C
- PHTHALHYDROQUINONE
- PHTHALIC ALCOHOL
- PYROCATCHUIC ACID
- PYROCATECHIN
- PYROCATECHINE
- PYROCATECHINIC ACID
- PYROCATECHOL