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Chemical Datasheet

1,4-BUTANEDIOL

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 110-63-4
none data unavailable
  • BUG
NIOSH Pocket Guide International Chem Safety Card
none
  • 1,4-BUTANEDIOL
NFPA 704
Diamond Hazard Value Description
1
1 0
Blue Health 1 Can cause significant irritation.
Red Flammability 1 Must be preheated before ignition can occur.
Yellow Instability 0 Normally stable, even under fire conditions.
White Special
(NFPA, 2010)
General Description
Odorless colorless liquid or solid (depending upon temperature). (USCG, 1999)

Hazards

Reactivity Alerts
none
Air & Water Reactions
This chemical is hygroscopic. Water soluble.
Fire Hazard
Special Hazards of Combustion Products: Carbon dioxide and carbon monoxide may be produced in fire.

Behavior in Fire: Unstable with heat; may form flammable tetrahydrofuran at 300°F. (USCG, 1999)
Health Hazard
Ingestion of large amounts needed to produce any symptoms. (USCG, 1999)
Reactivity Profile
1,4-BUTANEDIOL is heat and light sensitive. This compound reacts with acid chlorides, acid anhydrides and chloroformates. It also reacts with oxidizing agents and reducing agents. It is incompatible with isocyanates and acids. It is also incompatible with peroxides, perchloric acid, sulfuric acid, hypochlorous acid, nitric acid, caustics, acetaldehyde, nitrogen peroxide and chlorine. (NTP, 1992)
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below.

Response Recommendations

Isolation and Evacuation
No information available.
Firefighting
Fire Extinguishing Agents Not to Be Used: Water or foam may cause frothing.

Fire Extinguishing Agents: Alcohol foam, dry chemical or carbon dioxide. (USCG, 1999)
Non-Fire Response
No information available.
Protective Clothing
Eye protection and rubber gloves. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Physical Properties

Chemical Formula:
  • C4H10O2
Flash Point: 247°F (NTP, 1992)
Lower Explosive Limit (LEL): 1.9 % (USCG, 1999)
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: 671°F (USCG, 1999)
Melting Point: 61°F (NTP, 1992)
Vapor Pressure: less than 1 mmHg at 100°F (NTP, 1992)
Vapor Density (Relative to Air): 3.1 (NTP, 1992) - Heavier than air; will sink
Specific Gravity: 1.017 at 68°F (USCG, 1999) - Denser than water; will sink
Boiling Point: 446°F at 760 mmHg (NTP, 1992)
Molecular Weight: 90.12 (NTP, 1992)
Water Solubility: greater than or equal to 100 mg/mL at 73°F (NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Butanediol, 1,4-; (1,4-Tetramethylene glycol) (110-63-4) 4.7 mg/m3 52 mg/m3 640 mg/m3 LEL = 19500 ppm
(DOE, 2018)

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names