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Chemical Datasheet
NICKEL NITRATE |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 13478-00-7 (hexahydrate)
- 13138-45-9
- 14216-75-2
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NIOSH Pocket Guide |
International Chem Safety Card |
Nickel metal and other compounds (as Ni)
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none
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NFPA 704
data unavailable
General Description
Nickel nitrate is a green crystalline solid. It is soluble in water. It is noncombustible, but it will accelerate the burning of combustible materials. If large quantities are involved in a fire or the combustible material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. It is used in nickel plating and to make nickel catalysts for use in chemical manufacture.
Hazards
Reactivity Alerts
Air & Water Reactions
Soluble in water.
Fire Hazard
Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fire.
Behavior in Fire: May increase intensity of fire if in contact with combustible material (USCG, 1999)
Health Hazard
Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting. Dust irritates eyes and may cause dermatitis in contact with skin. (USCG, 1999)
Reactivity Profile
Green, crystalline material, toxic and carcinogenic. A powerful oxidizer, it may cause a violent reaction with reducing materials (e.g., magnesium or aluminum powder, tin(II) chloride). Dangerous fire hazard, acts as oxygen carrier. When heated to decomposition it emits highly toxic fumes of oxides of nitrogen [Lewis, 3rd ed., 1993, p. 915]. Complexes with tetrammine and tetrahydrazine are explosive [Bretherick, 5th ed., 1995, p. 1685].
Belongs to the Following Reactive Group(s)
- Nitrate and Nitrite Compounds, Inorganic
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been
known to react with the
absorbents
listed below.
- Cellulose-Based Absorbents
- Expanded Polymeric Absorbents
Response Recommendations
Isolation and Evacuation
Excerpt from 140
[Oxidizers]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. If ammonium nitrate is in a tank, rail car or tank truck and involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from 140
[Oxidizers]:
SMALL FIRE: Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.
LARGE FIRE: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to heat. If it can be done safely, move undamaged containers away from the area around the fire.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)
Non-Fire Response
Excerpt from 140
[Oxidizers]:
Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Do not get water inside containers.
SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.
SMALL LIQUID SPILL: Use a non-combustible material like vermiculite or sand to soak up the product and place into a container for later disposal.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. (ERG, 2020)
Protective Clothing
Bu. Mines approved respirator; rubber gloves; face shield or safety goggles; protective clothing (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
INHALATION: move to fresh air; got medical attention if exposure has been severe.
INGESTION: give large amount of water.
EYES: flush with water for at least 15 min.
SKIN: wash with soap and water. (USCG, 1999)
Physical Properties
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
2.05
at 68°F
(USCG, 1999)
- Denser than water; will sink
Boiling Point: data unavailable
Molecular Weight:
290.8
(hexahydrate)
(USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH:
10 mg Ni/m3
; A potential occupational carcinogen.
(NIOSH, 2023)
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Nickel(II) nitrate hexahydrate (13478-00-7)
|
1.5 mg/m3 |
53 mg/m3 |
320 mg/m3 |
Nickel(II) nitrate; (Nickelous nitrate) (13138-45-9)
|
0.93 mg/m3 |
10 mg/m3 |
61 mg/m3 |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
Nickel Compounds |
N495 |
|
|
& |
313 |
|
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Nickel nitrate |
14216-75-2 |
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100 pounds |
313c |
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(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- NICKEL BIS(NITRATE)
- NICKEL DINITRATE
- NICKEL NITRATE
- NICKEL NITRATE (NI(NO3)2)
- NICKEL NITRATE HEXAHYDRATE
- NICKEL(2+) NITRATE
- NICKEL(II) NITRATE
- NICKELOUS NITRATE