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Chemical Datasheet
METHYL CHLOROACETATE |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 96-34-4
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NIOSH Pocket Guide |
International Chem Safety Card |
none
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NFPA 704
General Description
A crystalline solid or a solid dissolved in a liquid. Insoluble in water and denser than water. Contact may slightly irritate skin, eyes and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.
Hazards
Reactivity Alerts
Air & Water Reactions
Highly flammable. Insoluble in water.
Fire Hazard
Special Hazards of Combustion Products: Toxic fumes of hydrogen chloride (USCG, 1999)
Health Hazard
Extremely corrosive to the eyes, skin, nose, throat, and upper respiratory tract. Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. (USCG, 1999)
Reactivity Profile
METHYL CHLOROACETATE is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Belongs to the Following Reactive Group(s)
- Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
- Halogenated Organic Compounds
Potentially Incompatible Absorbents
No information available.
Response Recommendations
Isolation and Evacuation
Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient. CAUTION: Methanol (UN1230) will burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.).
SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.
LARGE FIRE: Water spray, fog or alcohol-resistant foam. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal. Avoid aiming straight or solid streams directly onto the product.
FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)
Non-Fire Response
Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors.
SMALL SPILL: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Use clean, non-sparking tools to collect absorbed material.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2024)
Protective Clothing
Approved respirator, chemical safety goggles, chemical-resistant gloves, other protective clothing. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Call a physician.
EYES: Hold eyelids open, flush with running water for at least 15 minutes.
SKIN: Remove contaminated clothing and shoes. Flush affected areas with water for at least 15 minutes.
INHALATION: Move victim to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen.
INGESTION: Do nothing except keep victim warm. DO NOT INDUCE VOMITING (USCG, 1999)
Physical Properties
Flash Point:
125°F
(USCG, 1999)
Lower Explosive Limit (LEL):
7.5 %
(USCG, 1999)
Upper Explosive Limit (UEL):
18.5 %
(USCG, 1999)
Autoignition Temperature:
869°F
(USCG, 1999)
Melting Point:
-26°F
(USCG, 1999)
Vapor Pressure:
16.54 mmHg
(USCG, 1999)
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
1.2337
at 68°F
(USCG, 1999)
- Denser than water; will sink
Boiling Point:
266°F
at 760 mmHg
(USCG, 1999)
Molecular Weight:
108.52
(USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
No PAC information available.
Regulatory Information
EPA Consolidated List of Lists
No regulatory information available.
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- CHLOROACETIC ACID METHYL ESTER
- CHLOROACETIC ACID, METHYL ESTER
- METHYL 2-CHLOROACETATE
- METHYL ALPHA-CHLOROACETATE
- METHYL CHLOROACETATE
- METHYL MONOCHLORACETATE
- METHYL MONOCHLOROACETATE
- MONOCHLOROACETIC ACID METHYL ESTER
- MONOCHLOROACETIC ACID, METHYL ESTER