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Chemical Datasheet

P-CHLOROBENZOYL PEROXIDE

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 94-17-7
none data unavailable
  • DZP
NIOSH Pocket Guide International Chem Safety Card
none none
NFPA 704
data unavailable
General Description
Odorless white solid or paste. Sinks in water. (USCG, 1999)

Hazards

Reactivity Alerts
Air & Water Reactions
No rapid reaction with air. No rapid reaction with water.
Fire Hazard
Special Hazards of Combustion Products: Toxic chlorinated biphenyls are formed in fires.

Behavior in Fire: Solid may explode. Burns very rapidly when ignited. Smoke is unusually heavy when paste form is involved. (USCG, 1999)
Health Hazard
Irritates eyes and (on prolonged contact) skin. Ingestion causes irritation of mouth and stomach. (USCG, 1999)
Reactivity Profile
In pure crystalline form there is danger of explosion upon heating, shock, or friction. Peroxides are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

Response Recommendations

Isolation and Evacuation
No information available.
Firefighting
Fire Extinguishing Agents: Flood with water, or use dry chemical, foam, carbon dioxide. (USCG, 1999)
Non-Fire Response
No information available.
Protective Clothing
Goggles or face shield; rubber gloves; protective clothing. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: wash with water for at least 15 min.; consult a doctor.

SKIN: wash with soap and water.

INGESTION: induce vomiting and call a doctor. (USCG, 1999)

Physical Properties

Chemical Formula:
  • C14H8Cl2O4
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: greater than 1.1 at 68°F (USCG, 1999)
Boiling Point: data unavailable
Molecular Weight: 311.1 (USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

No PAC information available.

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names