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Chemical Datasheet
Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
|
none
|
data unavailable
|
|
NIOSH Pocket Guide |
International Chem Safety Card |
Chromic acid and chromates
|
none
|
NFPA 704
data unavailable
General Description
A yellow crystalline solid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used as a corrosion inhibitor and in the manufacture of other chemicals.
Hazards
Reactivity Alerts
Air & Water Reactions
Deliquescent. Water soluble
Fire Hazard
No information available.
Health Hazard
INHALATION: Corrosive to skin and mucous membranes causing dermatitis and slow healing ulcers. EYES: Conjunctivitis and lacrimation. INGESTION: Violent gastroenteritis, peripheral vascular collapse, vertigo, muscle cramps, coma, hemorrhagic diathesis, fever, liver damage and renal failure. (USCG, 1999)
Reactivity Profile
LITHIUM CHROMATE is an oxidizing agent. Can oxidize combustibles (USCG, 1999). Combining the chromate with zirconium can be explosive given the right proportions of reactants, [Z. Anorg., 1930, 191, 113].
Belongs to the Following Reactive Group(s)
- Salts, Basic
- Oxidizing Agents, Strong
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been
known to react with the
absorbents
listed below.
- Cellulose-Based Absorbents
- Expanded Polymeric Absorbents
Response Recommendations
Isolation and Evacuation
No information available.
Firefighting
No information available.
Non-Fire Response
No information available.
Protective Clothing
Approved filter-type respirator, close-fitting safety goggles, laboratory coat. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Call a doctor.
INHALATION: Move to fresh air.
EYES: Hold lids open and flush immediately with a slow stream of water. Continue for 10 to 15 minutes.
SKIN: Wash with large amounts of water then apply a paste of sodium bicarbonate.
INGESTION: Drink copious amounts of water. Administer a neutralizer like milk of magnesia, calcium hydroxide, etc. Do not induce vomiting. Call a physician. (USCG, 1999)
Physical Properties
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature:
Not flammable
(USCG, 1999)
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight:
165.92
(USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH:
15 mg Cr(VI)/m3
; A potential occupational carcinogen.
(NIOSH, 2023)
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Lithium chromate; (Lithium chromium oxide ) (14307-35-8)
|
0.37 mg/m3 |
6.5 mg/m3 |
39 mg/m3 |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
Chromium Compounds |
N090 |
|
|
& |
313 |
|
|
Lithium chromate |
14307-35-8 |
|
|
10 pounds |
313c |
|
|
(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- CHROMIC ACID, DILITHIUM SALT
- CHROMIUM LITHIUM OXIDE
- CHROMIUM LITHIUM OXIDE (CRLI2O4)
- DILITHIUM CHROMATE
- DILITHIUM CHROMATE (LI2CRO4)
- LITHIUM CHROMATE
- LITHIUM CHROMATE (LI2CRO4)
- LITHIUM CHROMATE(VI)
- LITHIUM CHROMIUM OXIDE (LI2CRO4)