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Chemical Datasheet

ETHYLENE GLYCOL MONOETHYL ETHER ACETATE

3 - Flammable liquid

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 111-15-9   (ETHYLENE GLYCOL MONOETHYL ETHER ACETATE)
  • 1172
  • Flammable Liquid
  • EGA
NIOSH Pocket Guide International Chem Safety Card
2-Ethoxyethyl acetate
  • 2-ETHOXYETHYL ACETATE
NFPA 704
Diamond Hazard Value Description
2
2 0
Blue Health 2 Can cause temporary incapacitation or residual injury.
Red Flammability 2 Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.
Yellow Instability 0 Normally stable, even under fire conditions.
White Special
(NFPA, 2010)
General Description
A clear colorless liquid with a pleasant odor. Flash point of 120°F. Less dense than water. Vapors are heavier than air.

Hazards

Reactivity Alerts
none
Air & Water Reactions
Flammable. Slightly soluble in water.
Fire Hazard
Excerpt from 129 Polymerizable warning [Flammable Liquids (Water-Miscible / Noxious)]:

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids will float on water. (ERG, 2020)
Health Hazard
Vapors irritate nose and eyes in high concentrations. Liquid irritates skin in prolonged or repeated contact. (USCG, 1999)
Reactivity Profile
Mixing ETHYLENE GLYCOL MONOETHYL ETHER ACETATE in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, oleum, and vinyl acetate, NFPA 1991.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

Response Recommendations

Isolation and Evacuation
Excerpt from 129 Polymerizable warning [Flammable Liquids (Water-Miscible / Noxious)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from 129 Polymerizable warning [Flammable Liquids (Water-Miscible / Noxious)]:

CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient.

SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane (UN1261) or nitroethane (UN2842).

LARGE FIRE: Water spray, fog or alcohol-resistant foam. Avoid aiming straight or solid streams directly onto the product. If it can be done safely, move undamaged containers away from the area around the fire.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)
Non-Fire Response
Excerpt from 129 Polymerizable warning [Flammable Liquids (Water-Miscible / Noxious)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material.

LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2020)
Protective Clothing
Excerpt from NIOSH Pocket Guide for 2-Ethoxyethyl acetate:

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.

Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: No recommendation is made specifying the need for the worker to change clothing after the workshift. (NIOSH, 2023)
DuPont Tychem® Suit Fabrics
Normalized Breakthrough Times (in Minutes)
Chemical CAS Number State QS QC SL C3 TF TP RC TK RF
Acetic acid 2 ethoxy ethyl ester 111-15-9 Liquid 116*/238 >480 >480 >480 >480 >480 >480
Ethoxy ethylacetat 111-15-9 Liquid 116*/238 >480 >480 >480 >480 >480 >480
Ethyl glycol acetate 111-15-9 Liquid 116*/238 >480 >480 >480 >480 >480 >480
Ethylene glycol mono ethyl ether acetate 111-15-9 Liquid 116*/238 >480 >480 >480 >480 >480 >480
> indicates greater than.
* indicates based on lowest single value.

Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

(DuPont, 2023)

First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Physical Properties

Chemical Formula:
  • C6H12O3
Flash Point: 135°F (NTP, 1992)
Lower Explosive Limit (LEL): 1.7 % (NTP, 1992)
Upper Explosive Limit (UEL): 6.7 % (NTP, 1992)
Autoignition Temperature: 715°F (USCG, 1999)
Melting Point: -79.1°F (NTP, 1992)
Vapor Pressure: 1.2 mmHg at 68°F ; 3.8 mmHg at 86°F (NTP, 1992)
Vapor Density (Relative to Air): 4.72 (NTP, 1992) - Heavier than air; will sink
Specific Gravity: 0.974 at 68°F (USCG, 1999) - Less dense than water; will float
Boiling Point: 313°F at 760 mmHg (NTP, 1992)
Molecular Weight: 132.16 (NTP, 1992)
Water Solubility: greater than or equal to 100 mg/mL at 66°F (NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: 500 ppm (NIOSH, 2023)

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Ethoxyethylacetate, 2- (111-15-9) 15 ppm 420 ppm 2500 ppm 1-flame icon indicates value is 10-49% of LEL. LEL = 17000 ppm
1-flame icon indicates value is 10-49% of LEL.
(DOE, 2018)

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names