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Chemical Datasheet
ETHYL ACETYLENE, STABILIZED |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 107-00-6
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none
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NIOSH Pocket Guide |
International Chem Safety Card |
none
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none
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NFPA 704
data unavailable
General Description
A colorless gas. Denser than air. Prolonged exposure to intense heat may cause the containers to rupture violently and rocket.
Hazards
Reactivity Alerts
- Highly Flammable
- Polymerizable
Air & Water Reactions
Highly flammable.
Fire Hazard
Excerpt from ERG Guide 116

[Gases - Flammable (Unstable); polymerization hazard]:
EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Acetylene (UN1001, UN3374) may react explosively even in the absence of air. Disilane (UN3553) and Silane (UN2203) will ignite spontaneously in air and may re-ignite. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket. (ERG, 2024)
Health Hazard
Excerpt from ERG Guide 116

[Gases - Flammable (Unstable); polymerization hazard]:
Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases. (ERG, 2024)
Reactivity Profile
ETHYL ACETYLENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic polymerization.
Belongs to the Following Reactive Group(s)
- Hydrocarbons, Aliphatic Unsaturated
- Alkynes, with Acetylenic Hydrogen
- Polymerizable Compounds
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been
known to react with the
absorbents
listed below.
- Mineral-Based & Clay-Based Absorbents
- Dirt/Earth
Response Recommendations
Isolation and Evacuation
Excerpt from ERG Guide 116

[Gases - Flammable (Unstable); polymerization hazard]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 800 meters (1/2 mile).
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions. (ERG, 2024)
Firefighting
Excerpt from ERG Guide 116

[Gases - Flammable (Unstable); polymerization hazard]:
DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
SMALL FIRE: Dry chemical or CO2.
LARGE FIRE: Water spray or fog. If it can be done safely, move undamaged containers away from the area around the fire.
FIRE INVOLVING TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)
Non-Fire Response
Excerpt from ERG Guide 116

[Gases - Flammable (Unstable); polymerization hazard]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. Do not touch or walk through spilled material. Do not direct water at spill or source of leak. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Isolate area until gas has dispersed. (ERG, 2024)
Protective Clothing
Excerpt from ERG Guide 116(P) [Gases - Flammable (Unstable); polymerization hazard]:
Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Excerpt from ERG Guide 116

[Gases - Flammable (Unstable); polymerization hazard]:
Refer to the "General First Aid" section. Specific First Aid: In case of contact with liquefied gas, only medical personnel should attempt thawing frosted parts. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. (ERG, 2024)
Physical Properties
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight:
54.0916
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
No PAC information available.
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
1-Butyne |
107-00-6 |
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10000 pounds |
Ethyl acetylene |
107-00-6 |
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10000 pounds |
(EPA List of Lists, 2024)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
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RELEASE |
THEFT |
SABOTAGE |
Chemical of Interest |
CAS Number |
Min Conc |
STQ |
Security Issue |
Min Conc |
STQ |
Security Issue |
Min Conc |
STQ |
Security Issue |
Ethyl acetylene; [1-Butyne] |
107-00-6 |
1.00 % |
10000 pounds |
flammable |
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(CISA, 2007)
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- 1-BUTYNE
- ETHYL ACETYLENE
- ETHYL ACETYLENE, STABILIZED
- ETHYL ACETYLENE, [STABILIZED]
- ETHYLACETYLENE
- ETHYLETHYNE