DIPHENYLOXIDE-4,4'-DISULFONYL HYDRAZIDE

A colorless, crystalline solid with a geranium-like odor. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. Moderately toxic by ingestion, inhalation and skin absorption. Readily ignited by sparks or flames and burns intensely and persistently.

none

Insoluble in water.

Excerpt from 149 [Substances (Self-Reactive)]:

Self-decomposition, self-polymerization, or self-ignition may be triggered by heat, chemical reaction, friction or impact. May be ignited by heat, sparks or flames. Some may decompose explosively when heated or involved in a fire. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. May burn violently. Decomposition or polymerization may be self-accelerating and produce large amounts of gases. Vapors or dust may form explosive mixtures with air. (ERG, 2020)

Excerpt from 149 [Substances (Self-Reactive)]:

Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce irritating, toxic and/or corrosive gases. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2020)

DIPHENYLOXIDE-4,4'-DISULFONYL HYDRAZIDE is an azide. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

• Azo, Diazo, Azido, Hydrazine, and Azide Compounds
• Ethers
• Sulfonates, Phosphonates, and Thiophosphonates, Organic

No information available.

Excerpt from 149 [Substances (Self-Reactive)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

LARGE SPILL: Consider initial evacuation for at least 250 meters (800 feet) in all directions.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)

Excerpt from 149 [Substances (Self-Reactive)]:

SMALL FIRE: Dry chemical, CO2, water spray or regular foam.

LARGE FIRE: Flood fire area with water from a distance. If it can be done safely, move undamaged containers away from the area around the fire.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: BEWARE OF POSSIBLE CONTAINER EXPLOSION. Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2020)

Excerpt from 149 [Substances (Self-Reactive)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch or walk through spilled material. Stop leak if you can do it without risk.

SMALL SPILL: Pick up with inert, damp, non-combustible material using clean, non-sparking tools and place into loosely covered plastic containers for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2020)

Excerpt from ERG Guide 149 [Substances (Self-Reactive)]:

Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2020)

No information available.

Excerpt from 149 [Substances (Self-Reactive)]:

Call 911 or emergency medical service. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air if it can be done safely. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. Keep victim calm and warm. (ERG, 2020)

• BENZENESULFONIC ACID, 4,4'-OXYDI-, DIHYDRAZIDE
• 4,4'-BIS(HYDRAZINOSULFONYL)DIPHENYL ETHER
• CELLMIC S
• CELOGEN OT
• CELOGEN TO
• DIHYDRAZIDE SDO
• DIPHENYL ETHER 4,4'-DISULFOHYDRAZIDE
• DIPHENYL OXIDE 4,4'-DISULFOHYDRAZIDE
• DIPHENYLOXIDE-4,4'-DISULFONYL HYDRAZIDE
• DIPHENYLOXIDE-4,4'-DISULPHONYL HYDRAZIDE
• FE 9
• GENITRON OB
• NEOCELLBORN FE 9
• NEOCELLBORN N 1000S
• NEOCELLBORN N 50
• NEOCELLBORN N 5000
• NEOCELLBORN P 1000
• NEOCELLBORN P 1000M
• OBSH
• 4,4'-OXYBIS(BENZENESULFONIC ACID HYDRAZIDE)
• 4,4'-OXYBIS(BENZENESULFONIC ACID) DIHYDRAZIDE
• 4,4'-OXYBIS(BENZENESULFONYL HYDRAZIDE)
• 4,4'-OXYDI(BENZENESULFONIC ACID HYDRAZIDE)
• 4,4'-OXYDIBENZENESULFONIC ACID DIHYDRAZIDE
• P,P'-OXYBIS(BENZENESULFOHYDRAZIDE)
• P,P'-OXYBIS(BENZENESULFONE HYDRAZIDE)
• P,P'-OXYBIS(BENZENESULFONYL HYDRAZIDE)
• P,P'-OXYBIS(BENZENESULFONYLHYDRAZINE)