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Chemical Datasheet
CHLOROTETRAFLUOROETHANE |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 63938-10-3 (mixed isomers)
- 2837-89-0 (2-chloro-1,1,1,2-tetrafluoroethane)
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NIOSH Pocket Guide |
International Chem Safety Card |
none
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none
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NFPA 704
data unavailable
General Description
Chlorotetrafluoroethane is a colorless odorless gas. It is shipped as a liquefied gas under its own vapor pressure. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. Exposure of the container to prolonged heat or fire can cause it to rupture violently and rocket.
Hazards
Reactivity Alerts
none
Air & Water Reactions
No rapid reaction with air. No rapid reaction with water.
Fire Hazard
Excerpt from 126
[Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket. CAUTION: Aerosols (UN1950) may contain a flammable propellant. (ERG, 2020)
Health Hazard
Displaces air such that oxygen content may become too low to support life. Prolonged exposure can cause narcotic effect or rapid suffocation. Contact with liquid may cause frostbite. (USCG, 1999)
Reactivity Profile
CHLOROTETRAFLUOROETHANE is chemically inert in many situations, but can react violently with strong reducing agents such as the very active metals and the active metals. Can react with strong oxidizing agents or weaker oxidizing agents under extremes of temperature.
Belongs to the Following Reactive Group(s)
- Fluorinated Organic Compounds
Potentially Incompatible Absorbents
No information available.
Response Recommendations
Isolation and Evacuation
Excerpt from 126
[Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 500 meters (1/3 mile).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from 126
[Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Use extinguishing agent suitable for type of surrounding fire.
SMALL FIRE: Dry chemical or CO2.
LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Damaged cylinders should be handled only by specialists.
FIRE INVOLVING TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. Some of these materials, if spilled, may evaporate leaving a flammable residue. (ERG, 2020)
Non-Fire Response
Excerpt from 126
[Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Do not touch or walk through spilled material. Stop leak if you can do it without risk. Do not direct water at spill or source of leak. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Allow substance to evaporate. Ventilate the area. (ERG, 2020)
Protective Clothing
Approved respirator, chemical safety goggles, chemical resistant gloves, other protective clothing (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Call a physician.
INHALATION: Move victim to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen.
SKIN OR EYES: Remove contaminated clothing and shoes, flush affected area with lukewarm water. DO NOT USE HOT WATER. (USCG, 1999)
Physical Properties
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature:
Not flammable
(USCG, 1999)
Melting Point:
-179°F
(USCG, 1999)
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point:
13.6°F
at 760 mmHg
(USCG, 1999)
Molecular Weight:
136.48
(USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
Chemical |
ERPG-1 |
ERPG-2 |
ERPG-3 |
HCFC-124 (2-Chloro-1,1,1,2-Tetrafluoroethane) (2837-89-0)
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1000 ppm |
5000 ppm |
10000 ppm |
(AIHA, 2022)
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Chloro-1,1,1,2-tetrafluoroethane, 2- (2837-89-0)
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1000 ppm |
5000 ppm |
10000 ppm |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
2-Chloro-1,1,1,2-tetrafluoroethane |
2837-89-0 |
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313 |
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Chlorotetrafluoroethane |
63938-10-3 |
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313 |
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HCFC-124 |
2837-89-0 |
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X |
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(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- 2-CHLORO-1,1,1,2-TETRAFLUOROETHANE
- 1-CHLORO-1,1,2,2-TETRAFLUOROETHANE
- 1-CHLORO-1,2,2,2-TETRAFLUOROETHANE
- CHLOROTETRAFLUOROETHANE
- F-124
- HALON 241
- HCFC-124
- MONOCHLOROTETRAFLUOROETHANE
- R-124
- REFRIGERANT GAS R-124
- TETRAFLUOROCHLOROETHANE
- TETRAFLUOROMONOCHLOROETHANE