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Chemical Datasheet

CAMPHOR

4.1 - Flammable solid

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 76-22-2
  • 2717
  • Flammable Solid
none
NIOSH Pocket Guide International Chem Safety Card
Camphor (synthetic)
  • CAMPHOR
NFPA 704
Diamond Hazard Value Description
2
2 0
Blue Health 2 Can cause temporary incapacitation or residual injury.
Red Flammability 2 Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.
Yellow Instability 0 Normally stable, even under fire conditions.
White Special
(NFPA, 2010)
General Description
A colorless or white colored crystalline powder with a strong mothball-like odor. About the same density as water. Emits flammable vapors above 150°F. Used to make moth proofings, pharmaceuticals, and flavorings.

Hazards

Reactivity Alerts
Air & Water Reactions
Highly flammable. Slightly soluble in water.
Fire Hazard
Excerpt from 133 Polymerizable warning [Flammable Solids]:

Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare-burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished. (ERG, 2020)
Health Hazard
Excerpt from 133 Polymerizable warning [Flammable Solids]:

Fire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2020)
Reactivity Profile
Naphthalene, CAMPHOR, glycerol, or turpentine will react violently with chromic anhydride [Haz. Chem. Data 1967 p. 68].
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

Response Recommendations

Isolation and Evacuation
Excerpt from 133 Polymerizable warning [Flammable Solids]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 25 meters (75 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from 133 Polymerizable warning [Flammable Solids]:

SMALL FIRE: Dry chemical, CO2, sand, earth, water spray or regular foam.

LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Fire Involving Metal Pigments or Pastes (e.g. "Aluminum Paste") Aluminum Paste fires should be treated as a combustible metal fire. Use DRY sand, graphite powder, dry sodium chloride-based extinguishers or class D extinguishers. Also, see 170 Polymerizable warning.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Cool containers with flooding quantities of water until well after fire is out. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2020)
Non-Fire Response
Excerpt from 133 Polymerizable warning [Flammable Solids]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch or walk through spilled material.

SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.

LARGE SPILL: Wet down with water and dike for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2020)
Protective Clothing
Excerpt from NIOSH Pocket Guide for Camphor (synthetic):

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.

Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: DAILY - Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. (NIOSH, 2023)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Excerpt from NIOSH Pocket Guide for Camphor (synthetic):

Eye: IRRIGATE IMMEDIATELY - If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

Skin: SOAP WASH IMMEDIATELY - If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.

Breathing: RESPIRATORY SUPPORT - If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the affected person warm and at rest. Get medical attention as soon as possible.

Swallow: MEDICAL ATTENTION IMMEDIATELY - If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2023)

Physical Properties

Chemical Formula:
  • C10H16O
Flash Point: 150°F (NIOSH, 2023)
Lower Explosive Limit (LEL): 0.6 % (NIOSH, 2023)
Upper Explosive Limit (UEL): 3.5 % (NIOSH, 2023)
Autoignition Temperature: data unavailable
Melting Point: 345°F (NIOSH, 2023)
Vapor Pressure: 0.2 mmHg (NIOSH, 2023)
Vapor Density (Relative to Air): data unavailable
Specific Gravity: 0.99 (NIOSH, 2023) - Less dense than water; will float
Boiling Point: 399°F at 760 mmHg (NIOSH, 2023)
Molecular Weight: 152.3 (NIOSH, 2023)
Water Solubility: Insoluble (NIOSH, 2023)
Ionization Energy/Potential: 8.76 eV (NIOSH, 2023)
IDLH: 200 mg/m3 (NIOSH, 2023)

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

No PAC information available.

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names