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Chemical Datasheet
3-BROMOPROPYNE |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 106-96-7
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none
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NIOSH Pocket Guide |
International Chem Safety Card |
none
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none
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NFPA 704
General Description
A colorless to light yellow liquid substance with a sharp odor. Flash point 65°F. Denser than water and insoluble in water. Vapors are heavier than air. May be irritating to skin and eyes. Used to make other chemicals. It may decompose explosively with mild shock.
Hazards
Reactivity Alerts
Air & Water Reactions
Highly flammable. Insoluble in water.
Fire Hazard
This material detonates at 428F or more; ignites by impact. Emits highly toxic fumes of bromides when heated to decomposition. Reacts vigorously with oxidizing materials. Becomes shock-sensitive when mixed with chloropicrin. Unstable, avoid heat, flame, shock, and other chemicals (EPA, 1998)
Health Hazard
This material is very toxic via the oral route. If inhaled, may be harmful; contact may cause burns to skin and eyes. (EPA, 1998)
Reactivity Profile
3-BROMOPROPYNE is soluble in alcohol, ether, chloroform, carbon tetrachloride and carbon disulfide. It is highly flammable and a dangerous fire risk, sensitive to shock. It is used in organic syntheses, preparation of resins and perfume intermediates [Hawley]. There is a high danger of formation of explosive metal acetylides, when this compound comes in contact with copper, high-copper alloys, mercury, or silver.
Belongs to the Following Reactive Group(s)
- Halogenated Organic Compounds
- Hydrocarbons, Aliphatic Unsaturated
- Alkynes, with Acetylenic Hydrogen
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been
known to react with the
absorbent
listed below.
Response Recommendations
Isolation and Evacuation
Excerpt from 130
[Flammable Liquids (Water-Immiscible / Noxious)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Wear self-contained breathing apparatus and full protective clothing. Move container from fire area if you can do it without risk. Do not get water inside container. Cool containers that are exposed to flames with water from the side until well after fire is out. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Isolate for 1/2 mile in all directions if tank car or truck is involved in fire.
To extinguish fire use water, foam, carbon dioxide, or dry chemical. (EPA, 1998)
Non-Fire Response
Excerpt from 130
[Flammable Liquids (Water-Immiscible / Noxious)]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2020)
Protective Clothing
For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Warning: Propargyl bromide is very toxic via the oral route, has corrosive effects, causes burns to skin and eyes, and is a strong lacrimating agent.
Signs and Symptoms of Propargyl Bromide Exposure: Signs and symptoms of acute exposure to propargyl bromide may include irritation or burning of eyes, nose, throat, respiratory tract with potential chemical pneumonitis or pulmonary edema, esophageal, GI tract, and skin irritations or burns. Kidney and hepatic injury has occurred in animals following exposure to propargyl bromide.
Emergency Life-Support Procedures: Acute exposure to propargyl bromide may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.
Inhalation Exposure:
1. Move victims to fresh air. Emergency personnel should avoid self-exposure to propargyl bromide.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
3. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures.
4. Transport to a health care facility.
Dermal/Eye Exposure:
1. Remove victims from exposure. Emergency personnel should avoid self-exposure to propargyl bromide.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
3. Remove contaminated clothing as soon as possible.
4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.
5. Wash exposed skin areas three times with soap and water.
6. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures.
7. Transport to a health care facility.
Ingestion Exposure:
1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
2. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures.
3. DO NOT induce vomiting.
4. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water.
5. Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims. Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults.
6. Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup). Water or milk should not be given if victims are not conscious and alert.
7. Transport to a health care facility. (EPA, 1998)
Physical Properties
Flash Point:
50°F
(EPA, 1998)
Lower Explosive Limit (LEL):
3 %
(EPA, 1998)
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point:
-77.9°F
(EPA, 1998)
Vapor Pressure: data unavailable
Vapor Density (Relative to Air):
4.1
(EPA, 1998)
- Heavier than air; will sink
Specific Gravity:
1.564 to 1.57
(EPA, 1998)
Boiling Point:
190 to 194°F
at 760 mmHg
(EPA, 1998)
Molecular Weight:
118.97
(EPA, 1998)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
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Propargyl bromide (106-96-7)
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1.4 mg/m3 |
63 mg/m3 |
380 mg/m3 |
LEL = 30000 ppm |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
Propargyl bromide |
106-96-7 |
10 pounds |
10 pounds |
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(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
Chemical Name |
CAS Number |
Threshold Quantity (TQ) |
3-Bromopropyne (also called Propargyl Bromide) |
106-96-7 |
100 pounds |
Propargyl Bromide |
106-96-7 |
100 pounds |
(OSHA, 2019)
Alternate Chemical Names
- 3-BROMO-1-PROPYNE
- 1-BROMO-2-PROPYNE
- BROMOPROPYNE
- 3-BROMOPROPYNE
- GAMMA-BROMOALLYLENE
- PROPARGYL BROMIDE
- PROPYNE, 3-BROMO-
- 2-PROPYNYL BROMIDE