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Chemical Datasheet

BENZOYL CHLORIDE

8 - Corrosive

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 98-88-4   (BENZOYL CHLORIDE)
  • 1736
  • Corrosive
  • BZC
NIOSH Pocket Guide International Chem Safety Card
none
  • BENZOYL CHLORIDE
NFPA 704
Diamond Hazard Value Description
2
3 2
W
Blue Health 3 Can cause serious or permanent injury.
Red Flammability 2 Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.
Yellow Instability 2 Readily undergoes violent chemical changes at elevated temperatures and pressures.
White Special W Reacts violently or explosively with water.
(NFPA, 2010)
General Description
A colorless fuming liquid with a pungent odor. Flash point 162°F. Lachrymator, irritating to skin and eyes. Corrosive to metals and tissue. Density 10.2 lb / gal. Used in medicine and in the manufacture of other chemicals.

Hazards

Reactivity Alerts
Air & Water Reactions
Fumes in air. Decomposes exothermically and rapidly in water to form insoluble benzoic acid and hydrochloric acid (HCl) [Merck 11th ed. 1989]. This is not supported by Argonne experiments which have not observed any gas generation upon mixing with water. Experimental work at Argonne National Laboratory has determined that there is no HCl formation; the substance was quite unreactive in water. This does not prevent HCl formation by a catalytic mechanism, but under normal conditions benzoyl chloride is quite unreactive. (Argonne Report ANL/DIS-00-1, October 2000).
Fire Hazard
Special Hazards of Combustion Products: Highly poisonous phosgene gas may be formed in fires.

Behavior in Fire: At fire temperatures the compound may react violently with water or steam. (USCG, 1999)
Health Hazard
INHALATION: may irritate eyes, nose and throat. INGESTION: causes acute discomfort. SKIN: causes irritation and burning. (USCG, 1999)
Reactivity Profile
BENZOYL CHLORIDE reacts violently with protic solvents such as alcohols, with amines and amides (for example dimethylformamide [Bretherick 1979 p. 6] ) and with inorganic bases. Causes the violent decomposition of dimethyl sulfoxide [Chem. Eng. News 35(9): 87 1957]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Friedel-Crafts acylation of naphthalene using benzoyl chloride, catalyzed by AlCl3, must be conducted above the melting point of the mixture, or the reaction may be violent [Clar, E. et al., Tetrahedron, 1974, 30, 3296].
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

Response Recommendations

Isolation and Evacuation
Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Firefighting
Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

When material is not involved in fire, do not use water on material itself.

SMALL FIRE: Dry chemical or CO2. Move containers from fire area if you can do it without risk.

LARGE FIRE: Flood fire area with large quantities of water, while knocking down vapors with water fog. If insufficient water supply: knock down vapors only.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)
Non-Fire Response
Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Use water spray to reduce vapors; do not put water directly on leak, spill area or inside container. Keep combustibles (wood, paper, oil, etc.) away from spilled material.

SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)
Protective Clothing
Full protective clothing, including full-face respirator for acid gases and organic vapors (yellow GMC canister), close-fitting goggles, nonslip rubber gloves, plastic apron, face shield. (USCG, 1999)
DuPont Tychem® Suit Fabrics
Normalized Breakthrough Times (in Minutes)
Chemical CAS Number State QS QC SL C3 TF TP BR RC TK RF
Benzoyl chloride (>95%) 98-88-4 Liquid >480 >480 >480 >480 >480 >480 >480
> indicates greater than.
A blank cell indicates the fabric has not been tested. The fabric may or may not offer barrier.

Special Warnings from DuPont

  1. Serged and bound seams are degraded by some hazardous liquid chemicals, such as strong acids, and should not be worn when these chemicals are present.
  2. CAUTION: This information is based upon technical data that DuPont believes to be reliable. It is subject to revision as additional knowledge and experience are gained. DuPont makes no guarantee of results and assumes no obligation or liability...

(DuPont, 2018)

First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and, in addition, have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. Transport the victim IMMEDIATELY to a hospital. (NTP, 1992)

Physical Properties

Chemical Formula:
  • C7H5ClO
Flash Point: 162 ° F (NTP, 1992)
Lower Explosive Limit (LEL): 1.2 % (NTP, 1992)
Upper Explosive Limit (UEL): 4.9 % (NTP, 1992)
Autoignition Temperature: data unavailable
Melting Point: 30.2 ° F (NTP, 1992)
Vapor Pressure: 0.4 mm Hg at 68 ° F ; 1 mm Hg at 89.8° F (NTP, 1992)
Vapor Density (Relative to Air): 4.88 (NTP, 1992)
Specific Gravity: 1.211 at 77 ° F (USCG, 1999)
Boiling Point: 387 ° F at 760 mm Hg (NTP, 1992)
Molecular Weight: 140.57 (NTP, 1992)
Water Solubility: Decomposes (NTP, 1992)
Ionization Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

Chemical ERPG-1 ERPG-2 ERPG-3
Benzoyl Chloride (98-88-4) 0.3 ppm star-in-circle icon indicates that odor should be detectable near ERPG-1. 5 ppm 20 ppm
star-in-circle icon indicates that odor should be detectable near ERPG-1.
(AIHA, 2016)

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Benzoyl chloride (98-88-4) 0.3 ppm 5 ppm 20 ppm LEL = 11000 ppm
(DOE, 2016)

Regulatory Information

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
Benzoyl chloride 98-88-4 1000 pounds 313

(EPA List of Lists, 2015)

DHS Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names