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Chemical Datasheet

DIETHYLENE GLYCOL DIETHYL ETHER

3 - Flammable liquid

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 112-36-7   (DIETHYLENE GLYCOL DIETHYL ETHER)
  • 1993
  • Flammable Liquid
none
NIOSH Pocket Guide International Chem Safety Card
none
  • DIETHYLENE GLYCOL DIETHYL ETHER
NFPA 704
Diamond Hazard Value Description
2
1 1
Blue Health 1 Can cause significant irritation.
Red Flammability 2 Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.
Yellow Instability 1 Normally stable but can become unstable at elevated temperatures and pressures.
White Special
(NFPA, 2010)
General Description
PHYSICAL DESCRIPTION: Clear colorless viscous liquid. (NTP, 1992)

Hazards

Reactivity Alerts
Air & Water Reactions
Highly flammable. May be sensitive to prolonged exposure to air. Can form explosive peroxides. Vapor-air mixtures are explosive above the flash point. Water soluble.
Fire Hazard
This chemical is combustible. (NTP, 1992)
Health Hazard
SYMPTOMS: Symptoms of exposure to this compound include irritation of the skin, eyes, mucous membranes and respiratory tract, coughing, dyspnea and kidney damage. Other symptoms may include nausea, vomiting, headache and central nervous system depression. Exposure may also cause diarrhea, abdominal and lumbar pain, mild liver damage, pulmonary edema, transient polyuria, oliguria, anuria and death by acute renal failure.

ACUTE/CHRONIC HAZARDS: This compound may be harmful by inhalation, ingestion or skin absorption. It is an irritant of the skin, eyes, mucous membranes and respiratory tract. When heated to decomposition it emits acrid smoke, irritating fumes and toxic fumes of carbon monoxide and carbon dioxide. (NTP, 1992)
Reactivity Profile
DIETHYLENE GLYCOL DIETHYL ETHER is incompatible with strong acids. It is also incompatible with strong oxidizing agents.(NTP, 1992)
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

Response Recommendations

Isolation and Evacuation
Excerpt from 128 Polymerizable warning [Flammable Liquids (Water-Immiscible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)
Protective Clothing
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Physical Properties

Chemical Formula:
  • C8H18O3
Flash Point: 130°F (NTP, 1992)
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: 401°F (NTP, 1992)
Melting Point: -47.7°F (NTP, 1992)
Vapor Pressure: 0.54 mmHg at 77°F (NTP, 1992)
Vapor Density (Relative to Air): 5.6 (NTP, 1992) - Heavier than air; will sink
Specific Gravity: 0.9063 at 68°F (NTP, 1992) - Less dense than water; will float
Boiling Point: 372°F at 760 mmHg (NTP, 1992)
Molecular Weight: 162.23 (NTP, 1992)
Water Solubility: greater than or equal to 100 mg/mL at 66°F (NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Bis(2-ethoxyethyl) ether; (Diethyl carbitol) (112-36-7) 15 mg/m3 160 mg/m3 980 mg/m3
(DOE, 2018)

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names