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Chemical Datasheet
BARIUM PERMANGANATE |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
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NIOSH Pocket Guide |
International Chem Safety Card |
none
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none
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NFPA 704
data unavailable
General Description
A purplish colored crystalline solid. Noncombustible, but accelerates burning of combustible material. Finely divided combustible materials may be explosive. May spontaneously ignite on contact with combustible liquids. Contact with sulfuric acid may result in fires or explosions. Used as a disinfectant and to make other permanganates.
Hazards
Reactivity Alerts
Air & Water Reactions
Soluble in water.
Fire Hazard
Behavior in Fire: Can increase the intensity of fire. (USCG, 1999)
Health Hazard
Inhalation or contact with eyes or skin causes irritation. Ingestion causes abdominal pain, nausea, vomiting, pallor, shortness of breath. (USCG, 1999)
Reactivity Profile
Acetic acid or acetic anhydride can explode with permanganates, such as BARIUM PERMANGANATE, if not kept cold [Von Schwartz 1918 p 34]. Explosions can occur when permanganates that have been treated with sulfuric acid come in contact with benzene, carbon disulfide, diethyl ether, ethyl alcohol, petroleum, or organic matter.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been
known to react with the
absorbents
listed below.
- Cellulose-Based Absorbents
- Expanded Polymeric Absorbents
Response Recommendations
Isolation and Evacuation
Excerpt from 141
[Oxidizers - Toxic]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from 141
[Oxidizers - Toxic]:
SMALL FIRE: Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.
LARGE FIRE: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to heat. If it can be done safely, move undamaged containers away from the area around the fire.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)
Non-Fire Response
Excerpt from 141
[Oxidizers - Toxic]:
Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk.
SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.
LARGE SPILL: Dike far ahead of spill for later disposal. (ERG, 2020)
Protective Clothing
Goggles or face shield; dust respirator; rubber gloves and shoes. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Get medical attention. Alert doctor to possibility of barium poisoning, particularly if compound was swallowed.
INHALATION: remove to fresh air.
EYES: flush with copious amounts of water for 15 min.
SKIN: wash with copious amounts of water.
INGESTION: induce vomiting; give a 10% water solution of Epsom salt. (USCG, 1999)
Physical Properties
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
3.77
at 68°F
(USCG, 1999)
- Denser than water; will sink
Boiling Point: data unavailable
Molecular Weight:
375
(USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Barium permanganate (7787-36-2)
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20 mg/m3 |
34 mg/m3 |
200 mg/m3 |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
Barium Compounds |
N040 |
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313 |
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Manganese Compounds |
N450 |
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& |
313 |
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(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
Chemical Name |
CAS Number |
Threshold Quantity (TQ) |
Ammonium Permanganate |
7787-36-2 |
7500 pounds |
(OSHA, 2019)
Alternate Chemical Names