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Chemical Datasheet

1-CHLORO-1-NITROPROPANE

6.1 - Poison

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 600-25-9   (1-CHLORO-1-NITROPROPANE)
  • 2810
  • Poison
  • CNE
NIOSH Pocket Guide International Chem Safety Card
1-Chloro-1-nitropropane
  • 1-CHLORO-1-NITROPROPANE
NFPA 704
Diamond Hazard Value Description
2
3 3
Blue Health 3 Can cause serious or permanent injury.
Red Flammability 2 Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.
Yellow Instability 3 Capable of detonation or explosive decomposition or explosive reaction but requires a strong initiating source or must be heated under confinement before initiation.
White Special
(NFPA, 2010)
General Description
Colorless liquid. Unpleasant odor. (USCG, 1999)

Hazards

Reactivity Alerts
Air & Water Reactions
Slightly soluble in water [Lawry's].
Fire Hazard
Combustible: May produce toxic gases, including nitrogen oxides, hydrogen chloride, and carbon monoxide. Will attack some plastics, rubber, and coatings. (USCG, 1999)
Health Hazard
LIQUID: Irritating to skin and eyes. Harmful if swallowed. (USCG, 1999)
Reactivity Profile
1-CHLORO-1-NITROPROPANE is sensitive to heat (may be explosive). This chemical is incompatible with oxidizers. It will attack some forms of plastics, rubber and coatings (NTP, 1992). Combustible: May produce toxic gases, including nitrogen oxides, hydrogen chloride, and carbon monoxide. Will attack some plastics, rubber, and coatings (USCG, 1999).
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

Response Recommendations

Isolation and Evacuation
Excerpt from 153 Polymerizable warning [Substances - Toxic and/or Corrosive (Combustible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Extinguish with dry chemicals, CO2, or alcohol foam. Use water spray to "knock down" vapors and cool exposed containers. (USCG, 1999)
Non-Fire Response
Keep people away; shut off ignition sources; call fire department; notify local health and pollution control agencies; protect water intakes. (USCG, 1999)
Protective Clothing
Excerpt from NIOSH Pocket Guide for 1-Chloro-1-nitropropane:

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.

Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: No recommendation is made specifying the need for the worker to change clothing after the workshift. (NIOSH, 2023)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Physical Properties

Chemical Formula:
  • C3H6ClNO2
Flash Point: 144°F (NTP, 1992)
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: 5.8 mmHg at 77°F (NTP, 1992)
Vapor Density (Relative to Air): 4.26 (NTP, 1992) - Heavier than air; will sink
Specific Gravity: 1.2 (USCG, 1999) - Denser than water; will sink
Boiling Point: 286 to 289°F at 760 mmHg (NTP, 1992)
Molecular Weight: 123.54 (NTP, 1992)
Water Solubility: 1 to 5 mg/mL at 72°F (NTP, 1992)
Ionization Energy/Potential: 9.90 eV (NIOSH, 2023)
IDLH: 100 ppm (NIOSH, 2023)

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

No PAC information available.

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names