HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED, WITH MORE THAN 60% HYDROGEN PEROXIDE

Diamond	Hazard	Value	Description
0 3 3 ox	Health	3	Can cause serious or permanent injury.
	Flammability	0	Will not burn under typical fire conditions.
	Instability	3	Capable of detonation or explosive decomposition or explosive reaction but requires a strong initiating source or must be heated under confinement before initiation.
	Special	OX	Possesses oxidizing properties.

A colorless liquid. Vapors may irritate the eyes and mucous membranes. Under prolonged exposure to fire or heat containers may violently rupture due to decomposition. Used to bleach textiles and wood pulp, in chemical manufacturing and food processing.

• Explosive
• Strong Oxidizing Agent

An aqueous solution.

Excerpt from 143 [Oxidizers (Unstable)]:

May explode from friction, heat or contamination. These substances will accelerate burning when involved in a fire. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react explosively with hydrocarbons (fuels). Containers may explode when heated. Runoff may create fire or explosion hazard. (ERG, 2020)

Excerpt from 143 [Oxidizers (Unstable)]:

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire may produce irritating and/or toxic gases. Toxic fumes or dust may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2020)

HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED, WITH MORE THAN 60% HYDROGEN PEROXIDE is a powerful oxidizing agent. Will react or decompose violently and exothermically with readily oxidizable materials or alkaline substances. May decompose violently in contact with iron, copper, chromium, and most other metals or their salts, which act as catalysts for this reaction, and with ordinary dust (which frequently contain rust, also a catalyst for this reaction). Stabilization operates against such reactions, but does not eliminate their possibility. Contact with combustible materials may result in their spontaneous ignition. Solutions containing over 30% hydrogen peroxide can detonate when mixed with organic solvents (such as acetone, ethanol, glycerol); the violence of the explosion increases with increasing concentration of the hydrogen peroxide. Concentration of solutions of hydrogen peroxide under vacuum led to violent explosions when the concentration was sufficiently high (>90%) [Bretherick 2nd ed., 1979]. Mixtures of aqueous hydrogen peroxide with 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73(1967); J, Org. Chem. 28:1893(1963)]. Hydrogen selenide and hydrogen peroxide undergo a very rapid reaction [Mellor 1:941(1946-1947)].

• Oxidizing Agents, Strong
• Water and Aqueous Solutions

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

• Cellulose-Based Absorbents
• Expanded Polymeric Absorbents

Excerpt from 143 [Oxidizers (Unstable)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)

Excerpt from 143 [Oxidizers (Unstable)]:

SMALL FIRE: Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.

LARGE FIRE: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to heat. If it can be done safely, move undamaged containers away from the area around the fire. Do not get water inside containers: a violent reaction may occur.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Cool containers with flooding quantities of water until well after fire is out. Dike runoff from fire control for later disposal. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)

Excerpt from 143 [Oxidizers (Unstable)]:

Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewers, basements or confined areas.

SMALL SPILL: Flush area with large amounts of water.

LARGE SPILL: DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2020)

Excerpt from ERG Guide 143 [Oxidizers (Unstable)]:

Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2020)

Normalized Breakthrough Times (in Minutes)

Chemical	CAS Number	State	QS	QC	SL	C3	TF	TP	RC	TK	RF
Hydrogen peroxide (30%)	7722-84-1	Liquid		>480	>480				>480	>480
Hydrogen peroxide (50%)	7722-84-1	Liquid		>480		>480	>480	>480
Hydrogen peroxide (70%)	7722-84-1	Liquid	>480	>480			>480	>480	>480	>480	>480

Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

(DuPont, 2023)

Excerpt from 143 [Oxidizers (Unstable)]:

Call 911 or emergency medical service. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air if it can be done safely. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. Contaminated clothing may be a fire risk when dry. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. Keep victim calm and warm. (ERG, 2020)

• HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED, WITH MORE THAN 60% HYDROGEN PEROXIDE