BENOMYL

PHYSICAL DESCRIPTION: Colorless to white crystals or off-white powder. Faint acrid odor. (NTP, 1992)

none

Insoluble in water.

Literature sources indicate that this chemical is nonflammable. (NTP, 1992)

Excerpt from NIOSH Pocket Guide for Benomyl:

Exposure Routes: Inhalation, ingestion, skin and/or eye contact

Symptoms: Irritation eyes, skin, upper respiratory system; skin sensitization; possible reproductive, teratogenic effects

Target Organs: Eyes, skin, respiratory system, reproductive system (NIOSH, 2023)

BENOMYL is incompatible with strong acids, peroxides and strong oxidizers. Decomposed by strong alkalis. Also decomposes on storage with water (NTP, 1992).

• Amides and Imides
• Amines, Phosphines, and Pyridines
• Carbamates

Use caution: Liquids with this reactive group classification have been known to react with the absorbent listed below.

• Mineral-Based & Clay-Based Absorbents

Excerpt from 171 [Substances (Low to Moderate Hazard)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

STORAGE PRECAUTIONS: You should store this chemical under refrigerated temperatures, and protect it from moisture. If possible, it would be prudent to store this compound under inert atmosphere. (NTP, 1992)

Excerpt from NIOSH Pocket Guide for Benomyl:

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.

Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: DAILY - Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises.

Provide:
• EYEWASH - Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation involving the wearing of eye protection.
• QUICK DRENCH - Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2023)

No information available.

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, administer a slurry of activated charcoal in water and simultaneously call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

• AGROCIT
• ARBORTRINE
• ARILATE
• BBC
• BC 6597
• BENEX
• BENLAT
• BENLATE
• BENLATE 50
• BENLATE 50 W
• BENLATE 50W
• BENOMYL
• BENOMYL 50 W
• BENOMYL-IMEX
• BENOSAN
• 2-BENZIMIDAZOLECARBAMIC ACID, 1-(BUTYLCARBAMOYL)-, METHYL ESTER
• BNM
• 1-(BUTYLCARBAMOYL)-2-BENZIMIDAZOLECARBAMIC ACID, METHYL ESTER
• CARBAMIC ACID, METHYL-, 1-(BUTYLCARBAMOYL)-2-BENZIMIDAZOLE ESTER
• D 1991
• DU PONT 1991
• F1991
• FIBENZOL
• FUNDASOL
• FUNDAZOL
• FUNDAZOL 50WP
• FUNGICIDE 1991
• FUNGICIDE D-1991
• FUNGOCHROM
• MBC
• METHYL 1-((BUTYLAMINO)CARBONYL)-1H-BENZIMIDAZOL-2-YL CARBAMATE
• METHYL 1-(BUTYLCARBAMOYL)-2-BENZIMIDAZOLECARBAMATE
• METHYL 1-(BUTYLCARBAMOYL)-2-BENZIMIDAZOLYLCARBAMATE
• METHYL 1-(BUTYLCARBAMOYL)BENZIMIDAZOL-2-YLCARBAMATE
• NS 02
• NS 02 (FUNGICIDE)
• NS O2
• TERSAN
• TERSAN 1991
• UZGEN