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Chemical Datasheet
DIISOPROPYLBENZENE (ALL ISOMERS) |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 25321-09-9 (mixed isomers)
- 99-62-7 (m-isomer)
- 100-18-5 (p-isomer)
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NIOSH Pocket Guide |
International Chem Safety Card |
none
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- DIISOPROPYLBENZENE (mixture)
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NFPA 704
General Description
Clear amber liquid with a sharp, penetrating odor. A mixture of three isomers (ortho, meta, and para).
Hazards
Reactivity Alerts
none
Air & Water Reactions
Insoluble in water.
Fire Hazard
Special Hazards of Combustion Products: Vapors may travel considerable distance to an ignition source and flash back. (USCG, 1999)
Health Hazard
Vapors and liquid are irritating to eyes, mucous membrane, and upper respiratory tract and can cause headache, narcosis and unconsciousness. Systemic effects can have a relatively long duration after exposure. Ingestion can be moderately to severely toxic. Liquid can cause defatting of skin and dermititis. (USCG, 1999)
Reactivity Profile
Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as DIISOPROPYLBENZENE (ALL ISOMERS), and strong oxidizing agents. Can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
No information available.
Response Recommendations
Isolation and Evacuation
Excerpt from 171
[Substances (Low to Moderate Hazard)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.
Fire Extinguishing Agents: Water spray, carbon dioxide, dry chemical, alcohol foam. (USCG, 1999)
Non-Fire Response
Excerpt from 171
[Substances (Low to Moderate Hazard)]:
Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. For Asbestos, avoid inhalation of dust. Cover spill with plastic sheet or tarp to minimize spreading. Do not clean up or dispose of, except under supervision of a specialist.
SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area.
SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later disposal.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2020)
Protective Clothing
Gloves impervious to aromatic hydrocarbon and splash-proof safety goggles. Approved organic cartridge respirator for exposure below 1,000 ppm. Full face piece is required above 500 ppm. Self-contained breathing apparatus or air supplied respirators above 1000 ppm. Clothing impervious to aromatic hydrocarbon. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
INHALATION: Call for medical aid. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
INGESTION: Do not induce vomiting.
EYES: Flush with lots of running water for 15 minutes, lifting lower and upper lids occasionally.
SKIN: Wash with soap and water. Remove contaminated clothing. (USCG, 1999)
Physical Properties
Flash Point:
170°F
(USCG, 1999)
Lower Explosive Limit (LEL):
0.9 %
(USCG, 1999)
Upper Explosive Limit (UEL):
6.5 %
(USCG, 1999)
Autoignition Temperature:
840°F
(USCG, 1999)
Melting Point:
1.4°F
(USCG, 1999)
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
0.86
(USCG, 1999)
- Less dense than water; will float
Boiling Point:
397 to 410°F
at 760 mmHg
(USCG, 1999)
Molecular Weight:
162.3
(USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Bis(1-methylethyl)benzene; (Diisopropylbenzene) (25321-09-9)
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3.4 mg/m3 |
38 mg/m3 |
230 mg/m3 |
Diisopropylbenzene, 1,3- (99-62-7)
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2 mg/m3 |
23 mg/m3 |
180 mg/m3 |
Bis(1-methylethyl)benzene, 1,4-; (p- or 1,4-Diisopropylbenzene) (100-18-5)
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2.7 mg/m3 |
30 mg/m3 |
180 mg/m3 |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
No regulatory information available.
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- BENZENE, DIISOPROPYL
- BIS-(1-METHYLETHYL)-BENZENE
- CUMENE BOTTOMS
- DIISOPROPYLBENZENE (ALL ISOMERS)
- DIPB