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Chemical Datasheet
Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 140-11-4
|
none
|
data unavailable
|
|
NIOSH Pocket Guide |
International Chem Safety Card |
none
|
|
NFPA 704
General Description
Colorless liquid with an odor of pears. (USCG, 1999)
Hazards
Reactivity Alerts
none
Air & Water Reactions
Insoluble in water.
Fire Hazard
This chemical is combustible. (NTP, 1992)
Health Hazard
Harmful if inhaled. May be harmful if swallowed or absorbed through the skin. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract. (USCG, 1999)
Reactivity Profile
BENZYL ACETATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. This chemical is incompatible with strong oxidizing agents. It is also incompatible with acids, bases and reducing agents. (NTP, 1992)
Belongs to the Following Reactive Group(s)
- Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
Potentially Incompatible Absorbents
No information available.
Response Recommendations
Isolation and Evacuation
No information available.
Firefighting
Fire Extinguishing Agents: Water spray, carbon dioxide, dry chemical, alcohol foam. (USCG, 1999)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
STORAGE PRECAUTIONS: You should protect this material from exposure to light. Keep it away from oxidizing materials and store it under refrigerated temperatures. (NTP, 1992)
Protective Clothing
Self-contained breathing apparatus, rubber boots and heavy rubber gloves. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital.
OTHER: Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring. Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)
Physical Properties
Flash Point:
195°F
(NFPA, 2010)
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature:
862°F
(NTP, 1992)
Melting Point:
-60.7°F
(NTP, 1992)
Vapor Pressure:
1 mmHg
at 113°F
; 10 mmHg at 189.7°F
(NTP, 1992)
Vapor Density (Relative to Air):
5.1
(NTP, 1992)
- Heavier than air; will sink
Specific Gravity:
1.04
(USCG, 1999)
- Denser than water; will sink
Boiling Point:
419.9°F
at 760 mmHg
(NTP, 1992)
Molecular Weight:
150.18
(NTP, 1992)
Water Solubility:
less than 1 mg/mL
at 73°F
(NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
No ERPG information available.
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Benzyl acetate (140-11-4)
|
30 ppm |
330 ppm |
2000 ppm |
(DOE, 2024)
Regulatory Information
EPA Consolidated List of Lists
No regulatory information available.
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- ACETIC ACID, BENZYL ESTER
- ACETIC ACID, PHENYLMETHYL ESTER
- (ACETOXYMETHYL)BENZENE
- ALPHA-ACETOXYTOLUENE
- BENZYL ACETATE
- BENZYL ETHANOATE
- NCI-C06508
- PHENYLMETHYL ACETATE