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Chemical Datasheet
HYDROCYANIC ACID, AQUEOUS SOLUTION, WITH NOT MORE THAN 20% HYDROGEN CYANIDE |
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Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 74-90-8
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none
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NIOSH Pocket Guide |
International Chem Safety Card |
Hydrogen cyanide
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- HYDROGEN CYANIDE, LIQUEFIED
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NFPA 704
General Description
Clear colorless aqueous solution of a gas. Has a faint odor of almonds. Can evolve hydrogen cyanide gas, which is (barely) lighter than air. Flame can flash back to the source of a gas leak very easily. Lethal doses of gas may be inhaled. Lethal doses of cyanide can be absorbed from the solution through the skin.
Hazards
Reactivity Alerts
Air & Water Reactions
No rapid reaction with air. No rapid reaction with water.
Fire Hazard
Excerpt from 154
[Substances - Toxic and/or Corrosive (Non-Combustible)]:
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. For electric vehicles or equipment, 147
(lithium ion batteries) or 138
(sodium batteries) should also be consulted. (ERG, 2020)
Health Hazard
Excerpt from 154
[Substances - Toxic and/or Corrosive (Non-Combustible)]:
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental contamination. (ERG, 2020)
Reactivity Profile
HYDROCYANIC ACID, AQUEOUS SOLUTION, WITH NOT MORE THAN 20% HYDROGEN CYANIDE reacts with acid to evolve hydrogen cyanide, a very poisonous colorless gas smelling of bitter almonds which is a deadly human poison by all routes. Carbon dioxide from the air is sufficiently acidic to liberate HCN from aqueous solutions of hydrocyanic acid [Lewis]. The solution also can evolve gaseous hydrogen cyanide when heated. Inhalation of gaseous HCN is quickly fatal by respiratory arrest. The gas forms flammable or explosive mixtures with air (may be difficult to ignite at lower concentrations). It presents an explosion hazard when heated with or exposed to other oxidizing agents and may polymerize explosively at elevated temperature (50-60°C) or in the presence of traces of alkali [Wohler, L. et al., Chem. Ztg., 1926, 50, p. 761, 781]. It reacts violently with acetaldehyde. During the preparation of imidoester hydrochlorides, hydrogen chloride was rapidly passed over an alcoholic solution of hydrogen cyanide. An explosion ensued, despite cooling of the process [J. Org. Chem., 1955, 20, 1573]. In the absence of a stabilizer (e.g. phosphoric acid) it may undergo explosively rapid spontaneous (autocatalytic) polymerization leading to a fire. The reaction is autocatalytic because of ammonia formation [Bond, J., Loss Prev. Bull., 1991, 101, p.3].
Belongs to the Following Reactive Group(s)
- Cyanides, Inorganic
- Acids, Weak
- Polymerizable Compounds
- Water and Aqueous Solutions
Potentially Incompatible Absorbents
Use caution: Liquids with this reactive group classification have been
known to react with the
absorbents
listed below.
- Mineral-Based & Clay-Based Absorbents
- Dirt/Earth
Response Recommendations
Isolation and Evacuation
Excerpt from 154
[Substances - Toxic and/or Corrosive (Non-Combustible)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 1613 datasheet.
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from 154
[Substances - Toxic and/or Corrosive (Non-Combustible)]:
SMALL FIRE: Dry chemical, CO2 or water spray.
LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2020)
Non-Fire Response
Excerpt from 154
[Substances - Toxic and/or Corrosive (Non-Combustible)]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2020)
Protective Clothing
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2020)
DuPont Tychem® Suit Fabrics
Normalized Breakthrough Times (in Minutes)
Chemical |
CAS Number |
State |
QS |
QC |
SL |
C3 |
TF |
TP |
RC |
TK |
RF |
Hydrogen cyanide (21°C, liquid) |
74-90-8 |
Liquid |
|
|
|
|
|
|
135 |
>480 |
135 |
Hydrogen cyanide (27°C, gaseous) |
74-90-8 |
Vapor |
|
|
|
30 |
|
|
>480 |
>480 |
>480 |
Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be
used around heat, flames, sparks or in potentially flammable or
explosive environments. Only...
(DuPont, 2023)
First Aid
Excerpt from 154
[Substances - Toxic and/or Corrosive (Non-Combustible)]:
Call 911 or emergency medical service. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air if it can be done safely. Give artificial respiration if victim is not breathing. Do not perform mouth-to-mouth resuscitation if victim ingested or inhaled the substance; wash face and mouth before giving artificial respiration. Use a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim calm and warm. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. (ERG, 2020)
Physical Properties
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight: data unavailable
Water Solubility: data unavailable
Ionization Energy/Potential:
13.60 eV
[From NPG: Hydrogen cyanide]
(NIOSH, 2023)
IDLH:
50 ppm
[From NPG: Hydrogen cyanide]
(NIOSH, 2023)
AEGLs (Acute Exposure Guideline Levels)
Final AEGLs for Hydrogen cyanide (74-90-8)
Exposure Period |
AEGL-1 |
AEGL-2 |
AEGL-3 |
10 minutes |
2.5 ppm |
17 ppm |
27 ppm |
30 minutes |
2.5 ppm |
10 ppm |
21 ppm |
60 minutes |
2 ppm |
7.1 ppm |
15 ppm |
4 hours |
1.3 ppm |
3.5 ppm |
8.6 ppm |
8 hours |
1 ppm |
2.5 ppm |
6.6 ppm |
(NAC/NRC, 2023)
ERPGs (Emergency Response Planning Guidelines)
Chemical |
ERPG-1 |
ERPG-2 |
ERPG-3 |
Hydrogen Cyanide (74-90-8)
|
NA |
10 ppm |
25 ppm |
(AIHA, 2022)
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
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Hydrogen cyanide; (Hydrocyanic acid) (74-90-8)
|
2 ppm |
7.1 ppm |
15 ppm |
LEL = 56000 ppm |
(DOE, 2018)
Regulatory Information
EPA Consolidated List of Lists
Regulatory Name |
CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ |
EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
Cyanide Compounds |
N106 |
|
|
& |
313 |
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Hydrocyanic acid |
74-90-8 |
100 pounds |
10 pounds |
10 pounds |
X |
P063 |
2500 pounds |
Hydrogen cyanide |
74-90-8 |
100 pounds |
10 pounds |
10 pounds |
313 |
P063 |
2500 pounds |
(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
|
RELEASE |
THEFT |
SABOTAGE |
Chemical of Interest |
CAS Number |
Min Conc |
STQ |
Security Issue |
Min Conc |
STQ |
Security Issue |
Min Conc |
STQ |
Security Issue |
Hydrocyanic acid |
74-90-8 |
1.00 % |
2500 pounds |
toxic |
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Hydrogen cyanide; [Hydrocyanic acid] |
74-90-8 |
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4.67 % |
15 pounds |
WME |
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(CISA, 2007)
OSHA Process Safety Management (PSM) Standard List
Chemical Name |
CAS Number |
Threshold Quantity (TQ) |
Hydrogen Cyanide, Anhydrous |
74-90-8 |
1000 pounds |
(OSHA, 2019)
Alternate Chemical Names
- CARBON HYDRIDE NITRIDE (CHN)
- EVERCYN
- FORMIC ANAMMONIDE
- FORMONITRILE
- HYDROCYANIC ACID
- HYDROCYANIC ACID, AQUEOUS SOLUTION, WITH NOT MORE THAN 20% HYDROGEN CYANIDE
- HYDROCYANIC ACID, [AQUEOUS SOLUTION < = 20% HYDROCYANIC ACID]
- HYDROGEN CYANIDE
- HYDROGEN CYANIDE, AQUEOUS SOLUTION, WITH NOT MORE THAN 20% HYDROGEN CYANIDE
- PRUSSIC ACID