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Chemical Datasheet

FUEL OIL, [NO. 6]

3 - Flammable liquid

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 68553-00-4
  • 1993 (domestic)
  • 1202 (international)
  • Flammable Liquid
  • OSX
NIOSH Pocket Guide International Chem Safety Card
none
  • Bunker fuel
NFPA 704
Diamond Hazard Value Description
2
1 0
Blue Health 1 Can cause significant irritation.
Red Flammability 2 Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.
Yellow Instability 0 Normally stable, even under fire conditions.
White Special
(NFPA, 2010)
General Description
Thick black liquid with the odor of tar. Liquid is shipped at elevated temperature. Insoluble in water and usually less dense than water. (USCG, 1999)

Hazards

Reactivity Alerts
none
Air & Water Reactions
Flammable. Insoluble in water.
Fire Hazard
Excerpt from 128 Polymerizable warning [Flammable Liquids (Water-Immiscible)]:

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids will float on water. Substance may be transported hot. For hybrid vehicles, 147 Polymerizable warning (lithium ion batteries) or 138 Polymerizable warning (sodium batteries) should also be consulted. If molten aluminum is involved, refer to 169 Polymerizable warning. (ERG, 2020)
Health Hazard
INGESTION: gastrointestinal irritation. ASPIRATION: pulmonary irritation is normally minimal but may become more severe several hours after exposure. (USCG, 1999)
Reactivity Profile
FUEL OIL, [NO. 6] may be incompatible with strong oxidizing agents such as nitric acid. Charring may occur followed by ignition of unreacted material and other nearby combustibles. In other settings, mostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, burns exothermically to produce mostly carbon dioxide and water.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

Response Recommendations

Isolation and Evacuation
Excerpt from 128 Polymerizable warning [Flammable Liquids (Water-Immiscible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Fire Extinguishing Agents Not to Be Used: Water may be ineffective

Fire Extinguishing Agents: Dry chemical, foam, or carbon dioxide (USCG, 1999)
Non-Fire Response
Excerpt from 128 Polymerizable warning [Flammable Liquids (Water-Immiscible)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material.

LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2020)
Protective Clothing
Protective gloves; goggles or face shield. (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
INGESTION: do NOT lavage or induce vomiting.

ASPIRATION: treatment probably not required; delayed development of pulmonary irritation can be detected by serial chest x-rays; consider prophylactic antibiotic regime if condition warrants.

EYES: wash with copious quantity of water.

SKIN: wipe off and wash with soap and water. (USCG, 1999)

Physical Properties

Chemical Formula: data unavailable
Flash Point: greater than 150°F (USCG, 1999)
Lower Explosive Limit (LEL): 1 % (USCG, 1999)
Upper Explosive Limit (UEL): 5 % (USCG, 1999)
Autoignition Temperature: 765°F (USCG, 1999)
Melting Point: 55°F (USCG, 1999)
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: 0.95 at 68°F (approx.) (USCG, 1999) - Less dense than water; will float
Boiling Point: 415 to 1093°F at 760 mmHg (USCG, 1999)
Molecular Weight: data unavailable
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

No PAC information available.

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names