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Chemical Datasheet
FUEL OIL, [DIESEL] |
|
Chemical Identifiers
CAS Number |
UN/NA Number |
DOT Hazard Label |
USCG CHRIS Code |
- 68334-30-5
- 68476-30-2
- 68476-31-3
- 68476-34-6
- 77650-28-3
|
- 1993
(domestic)
- 1202
(international)
|
|
|
NIOSH Pocket Guide |
International Chem Safety Card |
none
|
|
NFPA 704
General Description
A straw yellow to dark colored liquid with a petroleum-like odor. Flash point below 141°F. Less dense than water and insoluble in water. Hence floats on water. Vapors heavier than air.
Hazards
Reactivity Alerts
Air & Water Reactions
Flammable. Insoluble in water.
Fire Hazard
Combustible. (USCG, 1999)
Health Hazard
LIQUID: Irritating to skin and eyes. Harmful if swallowed. (USCG, 1999)
Reactivity Profile
Saturated aliphatic hydrocarbons, which are contained in FUEL OIL, [DIESEL], may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, they burn exothermically to produce carbon dioxide and water. May be ignited by strong oxidizers.
Belongs to the Following Reactive Group(s)
- Hydrocarbons, Aliphatic Saturated
Potentially Incompatible Absorbents
No information available.
Response Recommendations
Isolation and Evacuation
Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective.
SMALL FIRE: Dry chemical, CO2, water spray or regular foam. If regular foam is ineffective or unavailable, use alcohol-resistant foam.
LARGE FIRE: Water spray, fog or regular foam. If regular foam is ineffective or unavailable, use alcohol-resistant foam. Avoid aiming straight or solid streams directly onto the product. If it can be done safely, move undamaged containers away from the area around the fire.
FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. For petroleum crude oil, do not spray water directly into a breached tank car. This can lead to a dangerous boil over. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)
Non-Fire Response
Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2024)
Protective Clothing
Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)
DuPont Tychem® Suit Fabrics
Normalized Breakthrough Times (in Minutes)
Chemical |
CAS Number |
State |
QS |
QC |
SL |
C3 |
TF |
TP |
RC |
TK |
RF |
Diesel fuel |
68334-30-5 |
Liquid |
|
|
|
199 |
>480 |
>480 |
>480 |
>480 |
>480 |
Fuel-oil no 2 |
68476-30-2 |
Liquid |
|
imm |
>480 |
|
|
|
>480 |
|
|
Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be
used around heat, flames, sparks or in potentially flammable or
explosive environments. Only...
(DuPont, 2024)
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Physical Properties
Chemical Formula:
data unavailable
Flash Point:
125°F
(NTP, 1992)
Lower Explosive Limit (LEL):
1.3 %
(NTP, 1992)
Upper Explosive Limit (UEL):
6 %
(NTP, 1992)
Autoignition Temperature:
350 to 625°F
(USCG, 1999)
Melting Point:
0°F
(NTP, 1992)
Vapor Pressure:
2.17 mmHg
at 70°F
(USCG, 1999)
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
0.841
at 60.8°F
(USCG, 1999)
- Less dense than water; will float
Boiling Point:
540 to 640°F
at 760 mmHg
(NTP, 1992)
Molecular Weight: data unavailable
Water Solubility:
less than 1 mg/mL
at 66°F
(NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
Chemical |
ERPG-1 |
ERPG-2 |
ERPG-3 |
Diesel Fuel and Other Middle Distillate Fuels (68334-30-5)
|
300 mg/m3  |
1000 mg/m3 |
Not Established |
(AIHA, 2022)
PACs (Protective Action Criteria)
Chemical |
PAC-1 |
PAC-2 |
PAC-3 |
Diesel fuels; (includes diesel fuel No. 4 (68476-31-3), fuel oil No.2 (68476-30-2), fuel oil residual (68476-33-5) (68334-30-5)
|
300 mg/m3 |
1000 mg/m3 |
6000 mg/m3 |
(DOE, 2024)
Regulatory Information
EPA Consolidated List of Lists
No regulatory information available.
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.
OSHA Process Safety Management (PSM) Standard List
No regulatory information available.
Alternate Chemical Names
- DFM
- DIESEL FUEL
- DIESEL FUEL OIL
- DIESEL OIL, MEDIUM
- FUEL OIL
- FUEL OIL 1-D
- FUEL OIL 2-D
- FUEL OIL, [DIESEL]
- NCI-C54795
- OILS: DIESEL