Print
Chemical Datasheet

BUTYL, DECYL, CETYL, EICOSYL METHACRYLATE

3 - Flammable liquid

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 97-88-1   (N-BUTYL METHACRYLATE)
  • 2227
  • Flammable Liquid
  • DER
NIOSH Pocket Guide International Chem Safety Card
none
  • BUTYL METHACRYLATE
NFPA 704
Diamond Hazard Value Description
2
1 2
Blue Health 1 Can cause significant irritation.
Red Flammability 2 Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.
Yellow Instability 2 Readily undergoes violent chemical changes at elevated temperatures and pressures.
White Special
Note: NFPA ratings shown are for butyl methacrylate, CAS number 97-88-1.
(NFPA, 2010)
General Description
A colorless liquid with a mild odor. Less dense than water and insoluble in water. Hence floats on water. (USCG, 1999)

Hazards

Reactivity Alerts
Air & Water Reactions
Insoluble in water.
Fire Hazard
Behavior in Fire: Containers may explode. (USCG, 1999)
Health Hazard
Inhalation may cause nausea because of offensive odor. Contact with liquid causes irritation of skin. Ingestion causes irritation of mouth and stomach. (USCG, 1999)
Reactivity Profile
BUTYL, DECYL, CETYL, EICOSYL METHACRYLATE is a mixture of four esters of methacrylic acid. Reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction with basic (caustic) solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Polymerization may occur when heated, exposed to light or mixed with peroxides. Polymerization can generate large quantities of heat. (USCG, 1999).
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

Response Recommendations

Isolation and Evacuation
Excerpt from 130 Polymerizable warning [Flammable Liquids (Water-Immiscible / Noxious); polymerization hazard]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.

Fire Extinguishing Agents: Dry chemical, foam, carbon dioxide (USCG, 1999)
Non-Fire Response
Excerpt from 130 Polymerizable warning [Flammable Liquids (Water-Immiscible / Noxious); polymerization hazard]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material.

LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2020)
Protective Clothing
Self-contained respirator; impervious gloves; chemical splash goggles (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
INHALATION: Remove to fresh air, give oxygen or artificial respiration as required.

EYES: Flush with copious amounts of water for 15 min. and consult physician.

SKIN: Wash with soap and water.

INGESTION: Induce vomiting; call a physician. (USCG, 1999)

Physical Properties

Chemical Formula:
  • C8H14O2
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight: data unavailable
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Methyl butylacrylate, 2-; (Butyl methacrylate) (97-88-1) 19 mg/m3 210 mg/m3 1300 mg/m3
(DOE, 2018)

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names