Print
Chemical Datasheet

MERCURY IODIDE

6.1 - Poison

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 7774-29-0
  • 1638
  • Poison
  • MID
NIOSH Pocket Guide International Chem Safety Card
Mercury compounds [except (organo) alkyls] (as Hg) none
NFPA 704
data unavailable
General Description
A scarlet-red odorless tasteless powder. Sensitive to light. Insoluble in water and sinks in water. At elevated temperatures turns yellow but turns back to red upon cooling. Poison.

Hazards

Reactivity Alerts
none
Air & Water Reactions
Insoluble in water.
Fire Hazard
Special Hazards of Combustion Products: Fumes from fire may contain toxic mercury vapor. (USCG, 1999)
Health Hazard
All forms of exposure to this compound are hazardous. Acute systemic mercurialism may be fatal within a few minutes; death by uremic poisoning is usually delayed 5-12 days. Acute poisoning has resulted from inhaling dust concentrations of 1.2-8.5 mg/m 3 of air; symptoms include tightness and pain in chest, coughing, and difficulty in breathing. Ingestion causes necrosis, pain, vomiting, and severe purging. Contact with eyes causes ulceration of conjunctiv a and cornea. Contact with skin causes irritation and possible dermatitis; systemic poisoning can occur by absorption through skin. (USCG, 1999)
Reactivity Profile
MERCURY IODIDE is a mild reducing agent. Reacts with sodium azide to form mercury(II) azide, which is shock, friction, and heat sensitive.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

Response Recommendations

Isolation and Evacuation
Excerpt from 151 Polymerizable warning [Substances - Toxic (Non-Combustible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from 151 Polymerizable warning [Substances - Toxic (Non-Combustible)]:

SMALL FIRE: Dry chemical, CO2 or water spray.

LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal. Avoid aiming straight or solid streams directly onto the product.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)
Non-Fire Response
Excerpt from 151 Polymerizable warning [Substances - Toxic (Non-Combustible)]:

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2020)
Protective Clothing
Dust mask; goggles or face shield; protective gloves (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
INHALATION: remove to fresh air; get medical attention.

INGESTION: alimentary absorption is very rapid; action during first10-15 min. determines prognosis. Give egg whites, milk, or activated charcoal and induce vomiting; consult physician.

EYES: flush with water for at least 15 min.

SKIN: flush with water; wash with soap and water. (USCG, 1999)

Physical Properties

Chemical Formula:
  • HgI2
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: 495°F (USCG, 1999)
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: 6.3 at 68°F (USCG, 1999) - Denser than water; will sink
Boiling Point: 669°F at 760 mmHg (USCG, 1999)
Molecular Weight: 454.9 (USCG, 1999)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: 10 mg Hg/m3 (NIOSH, 2023)

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Mercuric iodide; (Mercury(II) iodide) (7774-29-0) 0.17 mg/m3 0.23 mg/m3 63 mg/m3
(DOE, 2018)

Regulatory Information

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
Mercury Compounds N458 & 313

(EPA List of Lists, 2022)

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names