NITRIC ACID, RED FUMING

Diamond	Hazard	Value	Description
0 4 1 ox	Health	4	Can be lethal.
	Flammability	0	Will not burn under typical fire conditions.
	Instability	1	Normally stable but can become unstable at elevated temperatures and pressures.
	Special	OX	Possesses oxidizing properties.

A pale yellow to reddish brown liquid generating red-brown fumes and having a suffocating odor. Very toxic by inhalation. Corrosive to metals or tissue. Prolonged exposure to low concentrations or short term exposure to high concentrations may result in adverse health effects.

Rate of onset: Immediate

Persistence: Hours - days

Odor threshold: ~1 ppm

Source/use/other hazard: Used in many industries; Very corrosive to skin/mucous membranes as well as metals & other materials.

• Strong Oxidizing Agent
• Known Catalytic Activity
• Water-Reactive

Fumes in air. Soluble in all proportions with water. Dissolution in water produces heat, fumes, and spattering.

Excerpt from 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. UN1796, UN1802, UN1826, UN2032, UN3084, UN3085, and, at concentrations above 65%, UN2031 may act as oxidizers. Also consult 140 . Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Substance may react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. (ERG, 2020)

Excerpt from 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air may release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental contamination. (ERG, 2020)

NITRIC ACID, RED FUMING is a powerful oxidizing agent and nitrating agent. Accelerates the burning of combustible material and may cause charring and then ignition of combustible materials. May ignite alcohols, amines, ammonia, beryllium alkyls, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols on contact [Bretherick 1979. p.174]. Can react violently with finely divided antimony [Pascal 10:504. 1931-34]. Reacts violently with bromine pentafluoride [Mellor 2, Supp. 1:172. 1956]. Reacts with hydrogen selenide and hydrogen sulfide with incandescence [Berichte 3:658]. Mixtures with finely divided magnesium are explosive [Pieters 1957 p. 28]. Oxidizes magnesium phosphide with incandescence [Mellor 8:842. 1946-47]. Mixtures with acetic anhydride containing over 50% nitric acid by mass may act as detonating explosives [BCISC 42:2. 1971]. An etching agent prepared with equal portions of acetone, nitric acid, and 75% aqueous acetic acid exploded four hours after it was prepared and placed in a closed bottle. The explosive material may have been tetranitromethane [Chem. Eng. News 38: 56. 1960]. Reacts violently with phosphine [Edin. Roy. Soc. 13:88. 1835]. Explodes in contact with phosphorus trichloride [Comp. Rend. 28:86]. Reacts exothermically with phthalic acid or phthalic anhydride in the presence of sulfuric acid to give potentially explosive phthaloyl nitrates or nitrites or nitro derivatives of these compounds [Chem. & Ind. 20:790. 1972]. Reacts energetically with sodium azide [Mellor 8, Supp 2:315. 1967]. Reacts with uranium with explosive violence [Katz and Rabinowitch 1951].

• Acids, Strong Oxidizing

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below.

• Cellulose-Based Absorbents
• Expanded Polymeric Absorbents

Excerpt from 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 2032 datasheet.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)

Excerpt from 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

Note: Some foams will react with the material and release corrosive/toxic gases.

SMALL FIRE: CO2 (except for Cyanides), dry chemical, dry sand, alcohol-resistant foam.

LARGE FIRE: Water spray, fog or alcohol-resistant foam. If it can be done safely, move undamaged containers away from the area around the fire. Avoid aiming straight or solid streams directly onto the product. Dike runoff from fire control for later disposal.

FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2020)

Excerpt from 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor-suppressing foam may be used to reduce vapors. DO NOT GET WATER INSIDE CONTAINERS. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements or confined areas.

SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2020)

Excerpt from NIOSH Pocket Guide for Nitric acid:

Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.

Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.

Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.

Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.

Change: No recommendation is made specifying the need for the worker to change clothing after the workshift.

Provide:
• EYEWASH (PH<2.5) - Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation involving the wearing of eye protection. (pH<2.5)
• QUICK DRENCH (PH<2.5) - Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (pH<2.5) (NIOSH, 2023)

Normalized Breakthrough Times (in Minutes)

Chemical	CAS Number	State	QS	QC	SL	C3	TF	TP	RC	TK	RF
Nitric acid (50%)	7697-37-2	Liquid						>480
Nitric acid (70%)	7697-37-2	Liquid	203	>480	>480		>480	105*/140	>480	>480	>480
Nitric acid (90%)	7697-37-2	Liquid				>480			>480	>480	>480
Nitric acid (>95%)	7697-37-2	Liquid					46			390

Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...

(DuPont, 2023)

Excerpt from NIOSH Pocket Guide for Nitric acid:

Eye: IRRIGATE IMMEDIATELY - If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

Skin: WATER FLUSH IMMEDIATELY - If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.

Breathing: RESPIRATORY SUPPORT - If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the affected person warm and at rest. Get medical attention as soon as possible.

Swallow: MEDICAL ATTENTION IMMEDIATELY - If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2023)

• AQUA FORTIS
• AZOTIC ACID
• HYDROGEN NITRATE
• NITAL
• NITRIC ACID
• NITRIC ACID (CONC 80% OR GREATER)
• NITRIC ACID (HONO2)
• NITRIC ACID, FUMING
• NITRIC ACID, RED FUMING
• NITRIC ACID, [FUMING]
• NITRYL HYDROXIDE