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Chemical Datasheet

AMMONIUM THIOSULFATE

Chemical Identifiers

CAS Number UN/NA Number DOT Hazard Label USCG CHRIS Code
  • 7783-18-8
none data unavailable
  • ATF
NIOSH Pocket Guide International Chem Safety Card
none none
NFPA 704
data unavailable
General Description
Ammonium thiosulfate is a white crystalline solid. It is very soluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. It is used in photography, in chemical analysis, and for many other uses.

Hazards

Reactivity Alerts
Air & Water Reactions
Hygroscopic. Very soluble in water.
Fire Hazard
Special Hazards of Combustion Products: Toxic ammonia, hydrogen sulfide, and oxides of nitrogen and sulfur may form in fires. (USCG, 1999)
Health Hazard
Inhalation of dust may irritate respiratory system. Ingestion could be harmful. Contact with eyes or skin may cause irritation. (USCG, 1999)
Reactivity Profile
AMMONIUM THIOSULFATE is sensitive to heat. This chemical is incompatible with magnesium and aluminum powder. Mixtures with sodium chlorate can cause an exothermic reaction which can then decompose explosively. (NTP, 1992). Reacts with strong oxidizers such as chlorates, nitrates, and nitrites to release toxic ammonia, hydrogen sulfide, and sulfur trioxide gases. Will not polymerize. Ammonia, hydrogen sulfide, and oxides of nitrogen and oxides of sulfur may form in fires (USCG, 1999).
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

Response Recommendations

Isolation and Evacuation
No information available.
Firefighting
No information available.
Non-Fire Response
No information available.
Protective Clothing
Respirator; rubber gloves; safety glasses; face shield; rubber apron, shield, or suit as necessary to prevent skin contact (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Physical Properties

Chemical Formula:
  • H8N2O3S2
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: Decomposes at 302°F (NTP, 1992)
Vapor Pressure: 0 mmHg (NTP, 1992)
Vapor Density (Relative to Air): data unavailable
Specific Gravity: 2 at 68°F (USCG, 1999) - Denser than water; will sink
Boiling Point: Decomposes (NTP, 1992)
Molecular Weight: 148.2 (NTP, 1992)
Water Solubility: 64 % at 68°F (NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Ammonium thiosulfate; (Ammonium hyposulfite) (7783-18-8) 12 mg/m3 130 mg/m3 790 mg/m3
(DOE, 2018)

Regulatory Information

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

Alternate Chemical Names