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Reactive Group Datasheet

Amines

What are reactive groups?

Reactive groups are categories of chemicals that typically react in similar ways because they are similar in their chemical structure. Each substance with a chemical datasheet has been assigned to one or more reactive groups, and CAMEO Chemicals uses the reactive group assignments to make its reactivity predictions. More Info...

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There are 938 chemical datasheets assigned to this reactive group.

Description

Flammability
Amines are generally high-boiling liquids or solids at room temperature and are not highly flammable. Methylamine is an exception, because it is a gas with a wide flammability range. Amines are combustible. The combustion of amines yields noxious NOx.
Reactivity
Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
Toxicity
Variable. Some are very poisonous; others are only slightly toxic. Many amines are skin irritants. Some amines are known sensitizers for small populations of humans and serve to cause chemically induced allergic reactions. The effects of such reactions can be dramatic at rather low concentrations.
Other Characteristics
Amines are organic compounds derived from ammonia (NH3) by the replacement of one or more of the three hydrogen atoms of NH3 with an organic group R. The R group may be either aromatic or aliphatic. Aromatic amines contain at least one aromatic R group; aliphatic amines contain all aliphatic groups. Many amines have unpleasantly fishy or putrid odors.
Examples
Methylamine, aniline, triethanolamine, hexamethylenetetramine, cyclohexylamine, xylidine, ethylaniline, pyridine, anisidine, diphenylamine, ethylenediamine.

Reactivity Documentation

Click on the links below to see how this reactive group is predicted to react when it is mixed with one of the 47 reactive groups. A variety of documentation about that reactive group pair will be displayed, including predicted hazards, predicted gas byproducts, and background materials and references used to make the predictions.

Mix Amines with: