Reactive Group Datasheet
Acids, Inorganic Oxidizing |
What are reactive groups?
Reactive groups are categories of chemicals that typically react in similar ways because they
are similar in their chemical structure. Each substance with a chemical datasheet has
been assigned to one or more reactive groups, and CAMEO Chemicals uses the reactive
group assignments to make its reactivity predictions.
More Info...
If you can't find a chemical in the database--but you know what reactive group it
belongs in--you can add the reactive group to MyChemicals instead in order to see the
reactivity predictions.
There are
61 chemical datasheets
assigned to this reactive group.
Description
Flammability
Materials in this group are generally nonflammable. They may accelerate the combustion of other materials by providing oxygen to the combustion site, that is, by serving as oxidizing agents.
Reactivity
Materials in this group are generally soluble in water with the release of hydrogen ions. The resulting solutions have pHs of less than 7.0. Materials in this group react with chemical bases (for example: amines and inorganic hydroxides) to form salts. These neutralization reactions occur as the base accepts hydrogen ions that the acid donates. Neutralizations can generate dangerously large amounts of heat in small spaces. The dissolution of acids in water or the dilution of their concentrated solutions with water may generate significant heat. The addition of water to acids often generates sufficient heat in the small region of mixing to boil some of the water explosively. The resulting "bumping" spatters acid widely. These materials have significant ability as oxidizing agents. but that ability varies (for example, from high for nitric acid to low for sulfuric acid and most sulfonic acids). They can react with active metals, including iron and aluminum, and also many less active metals, to dissolve the metal and liberate hydrogen and/or toxic gases. Like other acids, materials in this group can initiate polymerization in certain classes of organic compounds. Their reactions with cyanide salts and compounds release gaseous hydrogen cyanide. Flammable and/or toxic gases are also often generated by their reactions with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and weak or strong reducing agents. Additional gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and even carbonates: the carbon dioxide gas from the last is non-toxic but the heat and spattering from the reaction can be troublesome. Acids often catalyze (increase the rate) of chemical reactions.
Toxicity
Corrosive to tissue. Acid fumes irritate sensitive tissues (such as the eyes and respiratory system) especially severely.
Other Characteristics
Acids have a sour taste; they turn blue litmus red.
Examples
Sulfuric acid, nitric acid, perchloric acid, arsenic acid, chlorosulfonic acid, chromic acid, fluorosulfonic acid, chloric acid, nitrosulfuric acid, selenic acid, sulfurous acid.
Reactivity Documentation
Click on the links below to see how this reactive group is predicted to react
when it is mixed with one of the 47 reactive
groups. A variety of documentation about that reactive group pair will be
displayed, including predicted hazards, predicted gas byproducts, and
background materials and references used to make the predictions.
Mix Acids, Inorganic Oxidizing with:
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Acid Halides
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Acids, Inorganic Non-oxidizing
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Acids, Inorganic Oxidizing
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Alcohols and Polyols
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Aldehydes
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Amides and Imides, Organic
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Amines
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Anhydrides
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Azo, Diazo, and Azido Compounds
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Bases
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Carbamates
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Carboxylic Acids
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CFCs and HCFCs (chlorofluorocarbons and chlorofluorohydrocarbons)
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Chlorosilanes
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Cyanides, Inorganic
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Epoxides
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Esters
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Ethers
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Halogenated Organic Compounds
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Halogenating Agents, Strong
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Hydrocarbons, Aliphatic Saturated
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Hydrocarbons, Aliphatic Unsaturated
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Hydrocarbons, Aromatics
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Inorganic Compounds/Neither Reducing nor Oxidizing
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Inorganic Oxidizing Agents
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Inorganic Reducing Agents
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Insufficient Information for Classification
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Isocyanates and Isothiocyanates, Organic
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Ketones
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Metal Hydrides, Alkyls and Aryls
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Metals, Alkali, Very Active
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Metals, Elemental & Powder, Active
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Metals, Less Reactive
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Nitrides, Phosphides, Carbides, and Silicides, Inorganic
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Nitriles
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Nitrites, Nitrates, and Nitro Compounds, Organic
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Not Chemically Reactive
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Organometallics
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Peroxides, Organic
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Phenols, Cresols
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Phosphates and Thiophosphates, Organic
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Salts, Acidic Inorganic/Organic
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Salts, Basic Inorganic/Organic
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Sulfides, Inorganic
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Sulfides, Organic
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Thiocarbamate Esters and Salt/Dithiocarbamate Esters and Salts
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Water