Chemical data sheet for:
METHYL ETHYL KETONE PEROXIDE
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What is this information?
CAS Number - Chemical Abstract Service registry number. Unique identification number assigned to this chemical by the American Chemical Society.
UN/NA Number - The United Nations-North America number (also called UN number or DOT number). Four-digit number identifying an individual chemical or group of chemicals with similar characteristics. Required on shipping papers; often shown on placards or labels. This numbering system was developed by the U.S. Department of Transportation, and then became the UN standard system for classifying hazardous materials.
STCC Number - Standard Transportation Commodity Code. Sounds like "Stick number." Seven-digit chemical identification code used by the Association of American Railroads. A STCC number beginning with "49" indicates a hazardous material.
CHRIS Code - Three-letter code used by the U.S. Coast Guard to identify individual chemicals included in its
CHRIS (Chemical Hazards Response Information System) manual.
NFPA 704 - Diamond-shaped label containing codes indicating the level of the chemical's toxic, flammability, and reactivity hazard, along with special hazards such as water- and air-reactivity. See
a guide to the "NFPA diamond."
DOT Hazard Label - Required DOT hazard warning label for the chemical (e.g., "Flammable Liquid," "Corrosive"). This label must be displayed on shipped packages, railroad tank cars, and tank trucks according to specifications described in 49 CFR 172.
General Description - Brief description of the general appearance, behavior, and hazardousness of the chemical.
List of data sources.
| CAS Number | UN/NA Number | STCC Number | CHRIS Code |
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DOT Hazard Label: |
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General Description
Colorless liquid. Strong irritant to skin and tissue. Used as an initiator for room temperature cure of unsaturated polyester resins. (NOAA Reactivity 2007)
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What is this information?
Reactivity Alerts - Special alerts for chemicals that are especially reactive. See
a table of reactivity alerts and their definitions.
Air & Water Reactions - Special alerts for chemicals that react with air and/or water or moisture.
Fire Hazard - Description of the chemical's flammability, byproducts that may evolve if the chemical is burned, and risk of explosion.
Health Hazard - Description of the health hazards of the chemical, such as toxicity, flammability, and corrosivity.
Reactivity Profile - Description of the potential reactivity between the chemical and other chemicals, as well as its reactivity with air and water, and any other intrinsic reactive hazards (e.g., polymerizability, peroxidizability).
Reactive Groups - The reactive group, or groups, to which the chemical was assigned, based on its known chemistry. Reactive groups are categories of chemicals that react in similar ways because they are similar in their chemical structure.
Read more about reactive groups.
Special WMD note - For chemicals that historically have been used as weapons of mass destruction (WMDs) or that could be used as WMDs, a special note describes the physical clues that can help you to assess whether an attack has taken place.
List of data sources.
Reactivity Alerts
- Explosive
- Strong Oxidizing Agent
Air & Water Reactions
No rapid reaction with air.
No rapid reaction with water.
Fire Hazard
Behavior in Fire: Explosive. (USCG, 1999)
Health Hazard
Extremely destructive to tissue of the mucous membranes, upper respiratory tract, eyes, and skin. Symptoms of exposure include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. (USCG, 1999)
Reactivity Profile
METHYL ETHYL KETONE PEROXIDE is a strong oxidizing agent. May be ignited by heat, sparks or flame and undergoes self-accelerating decomposition. Explosive decomposition occurs at 230° F. Sensitive to sunlight. Ignition and/or explosion may occur if mixed with readily oxidizable materials. Reacts with combustible materials such as wood, cloth or organic materials, with chlorine, and with metals (iron, copper and their alloys and aluminum and its alloys). Incompatible with strong oxidizing agents, strong reducing agents, natural rubbers, synthetic rubbers and chemical accelerators. Incompatible with heavy metals, acids and bases. (NOAA REACTIVITY, 2007)
Belongs to reactive group(s)
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What is this information?
Fire Fighting - Response recommendations for fire incidents in which the chemical is involved.
Non-Fire Response - Response recommendations for incidents not involving fire, in which the chemical is involved.
Protective Clothing - General recommendations.
First Aid - Recommended first aid treatment for people exposed to the chemical.
List of data sources.
Fire Fighting
Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Keep run-off water out of sewers and water sources. (© AAR, 2003)
Non-Fire Response
Keep material out of water sources and sewers. Apply water spray or mist to knock down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents. Water spill: Use natural barriers or oil spill control booms to limit spill travel. Remove trapped material with suction hoses. (© AAR, 2003)
Protective Clothing
Skin: Wear appropriate personal protective clothing to prevent skin contact.
Eyes: Wear appropriate eye protection to prevent eye contact.
Wash skin: The worker should immediately wash the skin when it becomes contaminated.
Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Change: No recommendation is made specifying the need for the worker to change clothing after the work shift.
Provide: Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substance; this is irrespective of the recommendation involving the wearing of eye protection. Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2003)
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and, in addition, have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. Transport the victim IMMEDIATELY to a hospital. (NTP, 1992)
Flash Point:
180.0 ° F
(NTP, 1992)
Lower Explosive Limit: data unavailable
Upper Explosive Limit: data unavailable
Auto Ignition Temperature:
1032.0 ° F
Component 2 (83.33%: LACTOSE)
(NTP, 1992)
Melting Point: data unavailable
Vapor Pressure:
<0.01 mm Hg
at 68.0 ° F
Component 2 (83.33%: LACTOSE)
(NTP, 1992)
Vapor Density:
Component 2 (83.33%: LACTOSE): 6.69
(NTP, 1992)
Specific Gravity:
1.17
at 68.0 ° F
(USCG, 1999)
Boiling Point:
244.0 ° F
at 760 mm Hg
(Decomposes)
(NIOSH, 2003)
Molecular Weight:
Component 1 (16.67%: ADRIAMYCIN HYDROCHLORIDE): 176.24; Component 2 (83.33%: LACTOSE): 194.19
(NTP, 1992)
Water Solubility:
1-5 mg/mL
at 72° F
(NTP, 1992)
AEGL: data unavailable
ERPG: use TEEL data
| TEEL-1 |
TEEL-2 |
TEEL-3 |
| 0.2 ppm |
20.0 ppm |
20.0 ppm |
| (TEEL, 2003) |
IDLH: data unavailable
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What is this information?
Regulatory Names - Names under which this substance is regulated under Federal laws such as CERCLA ("Superfund"), EPCRA ("Title III of SARA"), RCRA, and the Clean Air Act of 1990.
CAA RMP - Indicates whether this chemical has been listed as a toxic, flammable, or explosive hazardous substance under Section 112(r) of the Clean Air Act. For listed chemicals, displays the Threshold Quantity listed in the Act. A facility is subject to the accidental release prevention provisions of the Act if more than the Threshold Quantity of at least one listed chemical is in a process at the facility.
CERCLA - Indicates whether this chemical is listed as a hazardous substance under CERCLA (40 CFR 302). For listed chemicals, displays the Reportable Quantity (RQ) listed in CERCLA. A facility must report spilled quantities in excess of the RQ to Federal, state, and local governments.
EPCRA 302 EHS - Indicates whether this chemical is an Extremely Hazardous Substance (EHS), identified by the U.S. Environmental Protection Agency as an acute inhalation toxic threat, and listed under EPCRA. For listed chemicals, displays the Threshold Planning Quantity listed in 40 CFR 355. When the storage quantity of an EHS chemical at a facility exceeds this threshold, the reporting, community right-to-know, and emergency planning requirements of EPCRA must be met.
TRI (EPCRA 313) - Indicates whether this chemical is included in a list of toxic chemicals covered under Section 313 of EPCRA. Facilities manufacturing, storing, or using at least one Section 313 chemical may be required to submit annual reports of the amount of each chemical released into the environment, either routinely or by accident (see 40 CFR 372).
RCRA chemical code - Four-character identification code assigned to this substance under the Resource Conservation and Recovery Act of 1976 (RCRA).
Regulatory Names
- METHYL ETHYL KETONE PEROXIDE
CAA RMP:
Not a regulated chemical.
CERCLA:
Regulated chemical with a Reportable Quantity of 10 pounds.
EPCRA 302 EHS:
Not a regulated chemical.
TRI (EPCRA 313):
Not a regulated chemical.
RCRA chemical code:
U160
- 2-BUTANONE PEROXIDE
- 2-BUTANONE, PEROXIDE
- BUTANOX LPT
- BUTANOX M 105
- BUTANOX M 50
- BUTANOX M50, M105, LPT
- CHALOXYD MEKP-HA 1
- CHALOXYD MEKP-HA 1, -LA 1
- CHALOXYD MEKP-LA 1
- COMPONENT 1: 2-BUTANONE PEROXIDE (45%)
- COMPONENT 2: DIMETHYL PHTHALATE
- DELTA X 9
- DIPROMETIL LA 50R
- ETHYL METHYL KETONE PEROXIDE
- ETHYLMETHYLKETONE PEROXIDE
- FR 222
- HI-POINT 180
- KAYAMEK A
- KAYAMEK M
- KETONOX
- LUCIDOL DDM 9
- LUCIDOL DELTA X
- LUPERSOL DDA 30
- LUPERSOL DDM
- LUPERSOL DDM 9
- LUPERSOL DELTA X
- LUPERSOL DELTA X 9
- LUPERSOL DHD 9
- LUPERSOL DNF
- LUPERSOL DSW
- MEK PEROXIDE
- MEKP
- MEKPO
- MEPOX
- MEPOX 55
- METHYL ETHYL KETONE HYDROPEROXIDE
- METHYLETHYLKETONE PEROXIDE
- PERMEK G
- PERMEK H
- PERMEK N
- PERÓXIDO DE METIL ETIL CETONA (DOT SPANISH)
- PEROXYDE DE MÉTHYLÉTHYLCÉTONE (DOT FRENCH)
- SUPEROX 46-710